Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology Campus UAB, Bellaterra, 08193 Barcelona, Spain.
Chem Commun (Camb). 2022 Sep 1;58(71):9894-9897. doi: 10.1039/d2cc03907a.
We report the synthesis of photoactive carbon monoxide-releasing coordination polymer particles through the assembly of Mn(I) carbonyl complexes with bis(imidazole) ligands. The use of Mn(I) carbonyl complexes as metallic nodes in the coordination network avoids the potential for aggregation-induced self-quenching, favouring their use in the solid state.
我们通过组装含双咪唑配体的锰（I）羰基配合物合成了具有光活性的一氧化碳释放配位聚合物颗粒。在配位网络中使用锰（I）羰基配合物作为金属节点可避免聚集诱导自猝灭的可能性，有利于其在固态中的应用。
