Mehmood Tariq, Khan Asad Ullah, Raj Dandamudi Kodanda Phani, Deng Shuguang, Helal Mohamed H, Ali Hazim M, Ahmad Zubair
Department of Chemical Engineering, COMSATS University Islamabad, Lahore Campus, Defence Road, Off Rawind Road, Punjab, Lahore, 54000, Pakistan.
School for Engineering of Matter, Transport and Energy, Arizona State University, 551 E. Tyler Mall, Tempe, AZ, 85287, United States.
Chemosphere. 2022 Nov;307(Pt 3):136045. doi: 10.1016/j.chemosphere.2022.136045. Epub 2022 Aug 14.
Various reported methods are devoted to nitrate removal from water over the years. However, recently researchers are focusing on developing the materials that offer bio-based, non-toxic, inexpensive and yet an efficient solution for water treatment. In this study, removal of nitrates from water was carried out using oil tea shells (OTS) as a biosorbent. OTS powder was impregnated with ZnCl and biochar was prepared which was further treated with Cetyltrimethylammonium bromide (CTAB), a cationic surfactant. Both the Langmuir and the Freundlich models were satisfied by the nitrate adsorption of OTS biochar. The adsorption capacity was measured at 15.6 mg/g when the circumstances were at their best. The pseudo-second-order model provided an accurate description of the kinetic data that were collected from batch trials. The adsorption yield goes up when by usage of more adsorbent, but it goes down when adsorption start with a higher concentration of nitrate. The strong basis of analytical equipments were used to characterize the OTS biosorbent. According to the findings of the research, surface-modified OTS biochar is an effective material for the removal of nitrate from aqueous solutions. This means that it has the potential to be utilized in water treatment as an adsorbent that is both inexpensive and kind to the natural environment. Removal of heavy metals and other organic pollutants, both from groundwater and wastewater using OTS biochar seems like a promising and interesting area of study.
多年来,已有多种方法用于去除水中的硝酸盐。然而,最近研究人员正致力于开发能够提供基于生物、无毒、廉价且高效的水处理解决方案的材料。在本研究中,使用油茶壳(OTS)作为生物吸附剂来去除水中的硝酸盐。OTS粉末用ZnCl浸渍后制备生物炭,再用阳离子表面活性剂十六烷基三甲基溴化铵(CTAB)进一步处理。OTS生物炭对硝酸盐的吸附符合朗缪尔模型和弗伦德利希模型。在最佳条件下,吸附容量测定为15.6mg/g。准二级模型准确描述了从批量试验中收集的动力学数据。使用更多吸附剂时吸附产率会提高,但从较高浓度硝酸盐开始吸附时产率会降低。使用强大的分析设备对OTS生物吸附剂进行表征。根据研究结果,表面改性的OTS生物炭是从水溶液中去除硝酸盐的有效材料。这意味着它有潜力作为一种既廉价又对自然环境友好的吸附剂用于水处理。使用OTS生物炭去除地下水和废水中的重金属及其他有机污染物似乎是一个有前景且有趣的研究领域。