High-performance degradable films of poly(lactic acid)/thermochromic microcapsule composites with thermochromic and energy storage functions via blown film process.

In this study, the polylactic acid (PLA)/reversible thermochromic microcapsule (TCM) packaging application film was successfully synthesized by the blown film process. White mineral oil (WMO) was used as a dispersant to prepare PLA/TCM extruded materials with different mass fractions, in which the mass fraction of TCM was up to 20 wt% and the structural, thermal, mechanical, barrier, thermochromic, and heat storage-release properties were evaluated. It was found that WMO had a plasticizing effect, the elongation at break and water vapor transmission rate of the films with the addition of 7 wt% TCM were increased by 533 % and 31.38 %, respectively. For each thermochromic film, significant thermochromic and energy storage release phenomena were observed. For instance, 20 wt% TCM thermochromic film was most effective for prolonging the holding time and suspending the temperature drop rate. In general, thermochromic packaging films with optimized constitutes were successfully synthesized by the blown film process, which provides essential reference significance for the large-scale thermochromic film applications.