Jiang Shan, Li Xiaokang, Fauqué Benoît, Behnia Kamran
Laboratoire de Physique et d'Étude des Matériaux, Ecole Supérieure de la Physique et de la Chimie Industrielles (ESPCI) Paris-CNRS-Sorbonne Université, PSL University, 75005 Paris, France.
Jeunes Equipes de l'Institut de Physique (JEIP), Unité de Service et de Recherche (USR) 3573 CNRS, Collège de France, Paris Sciences et Lettres (PSL) University, 75231 Paris Cedex 05, France.
Proc Natl Acad Sci U S A. 2022 Aug 30;119(35):e2201975119. doi: 10.1073/pnas.2201975119. Epub 2022 Aug 22.
SrTiO, a quantum paralectric, displays a detectable phonon thermal Hall effect (THE). Here, we show that the amplitude of the THE is extremely sensitive to stoichiometry. It drastically decreases upon substitution of a tiny fraction of Sr atoms with Ca, which stabilizes the ferroelectric order. It drastically increases by an even lower density of oxygen vacancies, which turn the system to a dilute metal. The enhancement in the metallic state exceeds by far the sum of the electronic and the phononic contributions. We explain this observation as an outcome of three features: 1) Heat is mostly transported by phonons; 2) the electronic Hall angle is extremely large; and 3) there is substantial momentum exchange between electrons and phonons. Starting from Herring's picture of phonon drag, we arrive to a quantitative account of the enhanced THE. Thus, phonon drag, hitherto detected as an amplifier of thermoelectric coefficients, can generate a purely thermal transverse response in a dilute metal with a large Hall angle. Our results reveal a hitherto-unknown consequence of momentum-conserving collisions between electrons and phonons.
量子顺电体SrTiO₃表现出可检测到的声子热霍尔效应(THE)。在此,我们表明THE的幅度对化学计量极其敏感。用Ca替代一小部分Sr原子时,THE幅度会急剧下降,这会使铁电序稳定。而氧空位密度更低时,THE幅度会急剧增加,这会使系统转变为稀金属。金属态下的增强幅度远远超过电子和声子贡献之和。我们将这一观察结果解释为三个特征的结果:1)热量主要由声子传输;2)电子霍尔角极大;3)电子和声子之间存在大量动量交换。从赫林的声子拖拽图景出发,我们对增强的THE进行了定量解释。因此,迄今被检测为热电系数放大器的声子拖拽,可在具有大霍尔角的稀金属中产生纯热横向响应。我们的结果揭示了电子和声子之间动量守恒碰撞的一个迄今未知的结果。