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基于淀粉和天然生物混合的热压智能标签。

Intelligent labels manufactured by thermo-compression using starch and natural biohybrid based.

机构信息

Department of Chemical and Food Engineering, Federal University of Santa Catarina, Florianópolis, SC, Brazil.

Department of Chemical and Food Engineering, Federal University of Santa Catarina, Florianópolis, SC, Brazil.

出版信息

Int J Biol Macromol. 2022 Nov 1;220:964-972. doi: 10.1016/j.ijbiomac.2022.08.127. Epub 2022 Aug 22.

Abstract

This work aims to develop intelligent labels based on cassava starch and biohybrid pigments by thermo-compression. The biohybrid pigment (BH) was developed by the adsorption of anthocyanins (ACNs) extracted from the jambolan fruit (Syzygium cumini L.) into montmorillonite (Mt) in order to improve its stability. The effect of the addition of biohybrid on the physicochemical properties of the thermo-pressed starch labels was evaluated. ACNs from jambolan extract show a visible pH-dependent color-changing ability at pH 1 - 12, and the adsorption did not modify the color property. The intelligent labels presented a homogeneous surface, and the BH was well dispersed in the starch matrix. The presence of BH increased the solubility in the water of starch labels. Chemical structure characterization revealed that the BH interacted with starch matrices through hydrogen bonds. Furthermore, the thermal stability of starch labels increased with the presence of BH. Hence, the purple color of intelligent labels was preserved at high temperatures. Finally, labels containing BH show visible changes from purple to a blue color when exposed to ammonia vapor, which simulates the degradation of meat products. Thus, the label content jambolan pigments will be used to control meat deterioration.

摘要

这项工作旨在通过热压法开发基于木薯淀粉和生物杂化颜料的智能标签。生物杂化颜料(BH)是通过将从乌饭树果实(Syzygium cumini L.)中提取的花色苷(ACNs)吸附到蒙脱石(Mt)上来开发的,以提高其稳定性。评估了生物杂化添加剂对热压淀粉标签理化性能的影响。来自乌饭树提取物的 ACNs 在 pH 1-12 时表现出可见的 pH 值依赖性变色能力,并且吸附不会改变颜色性质。智能标签表面均匀,BH 很好地分散在淀粉基质中。BH 的存在增加了淀粉标签在水中的溶解度。化学结构表征表明,BH 通过氢键与淀粉基质相互作用。此外,BH 的存在提高了淀粉标签的热稳定性。因此,智能标签的紫色在高温下得以保留。最后,当暴露于模拟肉类产品降解的氨蒸气时,含有 BH 的标签显示出从紫色到蓝色的可见变化。因此,标签中乌饭树色素的含量将用于控制肉类变质。

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