Self-cycled photo-Fenton-like system based on an artificial leaf with a solar-to-HO conversion efficiency of 1.46.

Millions of families around the world remain vulnerable to water scarcity and have no access to drinking water. Advanced oxidation processes (AOPs) are an effective way towards water purification with qualified reactive oxygen species (ROSs) while are impeded by the high-cost and tedious process in either input of consumable reagent, production of ROSs, and the pre-treatment of supporting electrolyte. Herein, we couple solar light-assisted HO production from water and photo-Fenton-like reactions into a self-cyclable system by using an artificial leaf, achieving an unassisted HO production rate of 0.77 μmol/(min·cm) under 1 Sun AM 1.5 illumination. Furthermore, a large (70 cm) artificial leaf was used for an unassisted solar-driven bicarbonate-activated hydrogen peroxide (BAP) system with recycled catalysts for real-time wastewater purification with requirements for only water, oxygen and sunlight. This demonstration highlights the feasibility and scalability of photoelectrochemical technology for decentralized environmental governance applications from laboratory benchtops to industry.