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通过使用ZnO/Zn前驱体薄膜控制锌升华法合成及表征纳米多孔ZnO薄膜

Synthesis and Characterization of Nanoporous ZnO Films by Controlling the Zn Sublimation by Using ZnO/Zn Precursor Films.

作者信息

Hernández-Rodríguez Yazmin Mariela, Lopez-Salazar Primavera, Juarez-Diaz Gabriel, Paredes-Rubio Gabriel Romero, Peña-Sierra Ramón

机构信息

Programa de Doctorado en Nanociencias y Nanotecnología, CINVESTAV-Instituto Politécnico Nacional, Av. IPN 2508, Mexico City 07360, Mexico.

Centro de Investigación en Dispositivos Semiconductores, Instituto de Ciencias, Benemérita Universidad Autónoma de Puebla, Ciudad Universitaria, Puebla 72570, Mexico.

出版信息

Materials (Basel). 2022 Aug 11;15(16):5509. doi: 10.3390/ma15165509.

DOI:10.3390/ma15165509
PMID:36013655
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9412365/
Abstract

A reliable process for the formation of nanoporous ZnO films supported on amorphous quartz and (100) silicon substrates via the processing of ZnO/Zn precursor films is reported. The process is based on the sublimation mechanism of Zn implemented in a novel ZnO/Zn precursor film to produce a nanoporous film. A scanning electron microscopy analysis of the nanoporous ZnO films' surfaces revealed the presence of ZnO nano-features with round tips; in contrast, the nanoporous ZnO films supported on (100) Si substrates showed hexagonal nut-like nanostructures. The crystallite size of the nanoporous ZnO films decreased as the sublimation temperature was increased. X-ray photoelectron spectroscopy studies demonstrated that formations of oxygen vacancies were produced during the processing stages (as the main structural lattice defects in the ZnO nanoporous films). The analysis of the photoluminescence response confirmed that the active deep-level centers were also related to the oxygen vacancies generated during the thermal processing of the ZnO/Zn precursor films. Finally, a qualitative mechanism is proposed to explain the formation of nanoporous ZnO films on quartz and crystalline Si substrates. The results suggest that the substrates used have a strong influence on the nanoporous ZnO structures obtained with the Zn-sublimation-controlled process.

摘要

报道了一种通过处理ZnO/Zn前驱体薄膜在非晶态石英和（100）硅衬底上形成纳米多孔ZnO薄膜的可靠工艺。该工艺基于在新型ZnO/Zn前驱体薄膜中实现的Zn升华机制来制备纳米多孔薄膜。对纳米多孔ZnO薄膜表面的扫描电子显微镜分析揭示了存在具有圆形尖端的ZnO纳米特征；相比之下，支撑在（100）Si衬底上的纳米多孔ZnO薄膜呈现出六边形螺母状纳米结构。随着升华温度的升高，纳米多孔ZnO薄膜的微晶尺寸减小。X射线光电子能谱研究表明，在处理阶段产生了氧空位（作为ZnO纳米多孔薄膜中的主要结构晶格缺陷）。光致发光响应分析证实，有源深能级中心也与ZnO/Zn前驱体薄膜热处理过程中产生的氧空位有关。最后，提出了一种定性机制来解释在石英和晶体Si衬底上纳米多孔ZnO薄膜的形成。结果表明，所用衬底对通过Zn升华控制工艺获得的纳米多孔ZnO结构有很大影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/5ca099508316/materials-15-05509-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/a44eb8bccecb/materials-15-05509-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/97e3f7642b73/materials-15-05509-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/1a9b02cd9f8e/materials-15-05509-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/0f3ea28cfe20/materials-15-05509-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/fb9a21440f7f/materials-15-05509-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/595d7b442002/materials-15-05509-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/5ca099508316/materials-15-05509-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/a44eb8bccecb/materials-15-05509-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/97e3f7642b73/materials-15-05509-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/1a9b02cd9f8e/materials-15-05509-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/0f3ea28cfe20/materials-15-05509-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/fb9a21440f7f/materials-15-05509-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/595d7b442002/materials-15-05509-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35e4/9412365/5ca099508316/materials-15-05509-g007.jpg

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2
Nanostructured Gas Sensors for Medical and Health Applications: Low to High Dimensional Materials.用于医疗和健康应用的纳米结构气体传感器：从低维到高维材料。
Biosensors (Basel). 2019 Mar 17;9(1):43. doi: 10.3390/bios9010043.
3
Fabrication of Well-Aligned ZnO Nanorods Using a Composite Seed Layer of ZnO Nanoparticles and Chitosan Polymer.
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Materials (Basel). 2013 Sep 30;6(10):4361-4374. doi: 10.3390/ma6104361.
4
The growth of ZnO on stainless steel foils by MOCVD and its application in light emitting devices.
Phys Chem Chem Phys. 2016 Feb 21;18(7):5614-21. doi: 10.1039/c5cp06826f. Epub 2016 Feb 1.
5
High efficiency dye-sensitized solar cells exploiting sponge-like ZnO nanostructures.利用海绵状 ZnO 纳米结构提高染料敏化太阳能电池的效率。
Phys Chem Chem Phys. 2012 Dec 21;14(47):16203-8. doi: 10.1039/c2cp42705b. Epub 2012 Oct 2.
6
Inverted polymer solar cells integrated with a low-temperature-annealed sol-gel-derived ZnO Film as an electron transport layer.集成有低温退火溶胶-凝胶衍生的ZnO薄膜作为电子传输层的倒置聚合物太阳能电池。
Adv Mater. 2011 Apr 12;23(14):1679-83. doi: 10.1002/adma.201004301. Epub 2011 Feb 22.
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Low-temperature, high-performance solution-processed metal oxide thin-film transistors formed by a ‘sol–gel on chip’ process.低温、高性能溶液处理金属氧化物薄膜晶体管由“芯片上溶胶-凝胶”工艺形成。
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8
Transition levels of defect centers in ZnO by hybrid functionals and localized basis set approach.杂化泛函和局域基组方法研究 ZnO 中缺陷中心的跃迁能级。
J Chem Phys. 2010 Oct 14;133(14):144512. doi: 10.1063/1.3491271.
9
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