School of Resources and Environmental Engineering, Anhui University, Hefei 230601, China.
Anhui Province Engineering Laboratory for Mine Ecological Remediation, Hefei 230601, China.
Molecules. 2022 Aug 22;27(16):5340. doi: 10.3390/molecules27165340.
In this study, the surface of vermiculite-montmorillonite was modified by MnO loading. The modified vermiculite-montmorillonite was added to remediate the potentially toxic trace element (PTE) Hg present in soil containing coal gangue. Pot experiments were conducted to analyze and compare the pH values, Hg contents and Hg species present in coal gangue-containing soil, with and without the modified materials added, to determine whether the addition of modified materials had an effect on the growth of L. Results showed that with the addition of 35 g·kg modified vermiculite-montmorillonite, the pH of soil increased by a value of 0.79, compared with that in the control group. When 15 g·kg was added, the concentration of Hg in soil decreased by 98.2%. The addition of modified materials promoted the transformation of Hg in soil from a bioavailable form to an unavailable form; that is, the content of the residual form increased. The plant height and biomass of L. also increased, which indicated that the addition of modifiers can increase soil productivity, reduce the effects of PTEs on organisms in soil, and promote plant growth. Therefore, the addition of modified vermiculite-montmorillonite can achieve remediation of coal gangue-containing soil.
在这项研究中,通过负载 MnO 对蛭石-蒙脱石的表面进行了改性。将改性后的蛭石-蒙脱石添加到含有煤矸石的土壤中,以修复潜在有毒微量元素(PTE)Hg。进行了盆栽实验,分析和比较了添加和不添加改性材料的含煤矸石土壤中的 pH 值、Hg 含量和 Hg 形态,以确定添加改性材料是否会影响 L 的生长。结果表明,添加 35 g·kg 的改性蛭石-蒙脱石后,土壤的 pH 值比对照组增加了 0.79。添加 15 g·kg 时,土壤中 Hg 的浓度降低了 98.2%。改性材料的添加促进了土壤中 Hg 从生物可利用形式向不可用形式的转化,即残留形式的含量增加。L. 的株高和生物量也增加了,这表明添加改性剂可以提高土壤生产力,降低 PTE 对土壤中生物的影响,促进植物生长。因此,添加改性蛭石-蒙脱石可以实现对含煤矸石土壤的修复。