Effective Removal of Methylene Blue by Surface Alteration of TiO with Ficus Carica Leaf Extract under Visible Light.

The present study describes the use of a leaf extract from as a source of natural antioxidants for the surface alteration of bulk titanium dioxide (TiO) in two steps. First, the hydro-thermal treatment of the bulk TiO material was carried out and followed by thermal annealing at 300 °C for 3 h in air. The role of the leaf extract of on the performance of the bulk TiO material for the removal of methylene blue (MB) was also studied. Various analytical techniques such as powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) were used to explore the crystalline structure, morphology, and composition. The bulk TiO material after the leaf-extract treatment exhibited mixed anatase and rutile phases, a flower-like morphology, and Ti, O, and C were its main elements. The average crystallite size was also calculated, and the obtained values for the bulk TiO material, 18.11 nm, and the treated bulk TiO material with various amounts, 5, 10, and 15 mL, of leaf extract were 16.4, 13.16, and 10.29 nm respectively. Moreover, Fourier-transform infrared spectroscopy validated the typical metal-oxygen bonds and strengthened the XRD results. The bulk TiO material chemically treated with has shown outstanding activity towards the degradation of MB under sunlight. The 15 mL of extract significantly enhanced the photocatalytic activity of the bulk TiO material towards the degradation of MB. The dye degradation efficiency was found to be 98.8%, which was experimentally proven by the Fourier Transform Infrared spectroscopoyy (FTIR) analysis. The obtained performance of the bulk TiO material with revealed excellent surface modifying properties for poorly-performing photocatalysts towards the degradation of synthetic dyes when used in their pristine form. The presented approach suggests that could be of great interest for tuning the surface properties of materials, either in the form of nano-size or bulk-phase in a particular application.