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复合驱油剂乳化性能的测试与评价

Testing and Evaluation of the Emulsifying Properties of Compound Oil Displacement Agents.

作者信息

Zhang Leilei, Wang Keliang, An Huiming, Su Yu, Zhang Wei, Li Gen, Yang Xinyi

机构信息

Key Laboratory of Enhanced Oil and Gas Recovery Ministry of Education, Northeast Petroleum University, Daqing 163318, China.

Baili College of Petroleum Engineering, Lanzhou City University, Lanzhou 730070, China.

出版信息

ACS Omega. 2022 Aug 10;7(33):29406-29414. doi: 10.1021/acsomega.2c03653. eCollection 2022 Aug 23.

DOI:10.1021/acsomega.2c03653
PMID:36033671
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9404487/
Abstract

Aiming at the phenomenon that the emulsification degree of the composite oil displacement agents affects the recovery factor, composite oil displacement agents of the P/S binary system and the A/S/P ternary system were taken as research objects. Emulsion particle size and stability were tested and evaluated, and the effects of the surfactant and alkali content on the emulsification degree of emulsion were investigated. The concept of the emulsification stability index and its measuring method were put forward, and a method was used to test and evaluate the emulsification stability of the emulsion. The results showed that the emulsion formed by the ternary system had the smallest average particle size, the best stability, and the best emulsification stability. The binary composite system was second, and the polymer solution did not form an emulsion. The emulsification stability index method could effectively quantify the emulsification degree of the emulsion. Within a certain range, the increase of the surfactant and alkali content in the composite oil displacement agent was beneficial to the improvement of the emulsification degree of the emulsion.

摘要

针对复合驱油剂乳化程度影响采收率的现象,以P/S二元体系和A/S/P三元体系复合驱油剂为研究对象。对乳液粒径和稳定性进行了测试与评价,考察了表面活性剂和碱含量对乳液乳化程度的影响。提出了乳化稳定性指数的概念及其测定方法,并采用该方法对乳液的乳化稳定性进行了测试与评价。结果表明,三元体系形成的乳液平均粒径最小,稳定性最好,乳化稳定性最佳。二元复合体系次之,聚合物溶液未形成乳液。乳化稳定性指数法能有效量化乳液的乳化程度。在一定范围内,复合驱油剂中表面活性剂和碱含量的增加有利于乳液乳化程度的提高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/4b169b034a08/ao2c03653_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/cd2089618f14/ao2c03653_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/56fa6b0a43bd/ao2c03653_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/6fefcaf87a22/ao2c03653_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/258f0cd56918/ao2c03653_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/0c7fbe845312/ao2c03653_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/d012f5e55b67/ao2c03653_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/4b169b034a08/ao2c03653_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/cd2089618f14/ao2c03653_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/56fa6b0a43bd/ao2c03653_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/6fefcaf87a22/ao2c03653_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/258f0cd56918/ao2c03653_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/0c7fbe845312/ao2c03653_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/d012f5e55b67/ao2c03653_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c2b5/9404487/4b169b034a08/ao2c03653_0008.jpg

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本文引用的文献

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Investigation of Brine pH Effect on the Rheological and Viscoelastic Properties of HPAM Polymer for an Optimized Enhanced Oil Recovery Design.研究盐水pH值对用于优化强化采油设计的HPAM聚合物流变学和粘弹性性质的影响。
ACS Omega. 2022 Apr 19;7(17):14961-14971. doi: 10.1021/acsomega.2c00699. eCollection 2022 May 3.
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Emulsification and emulsion stability: The role of the interfacial properties.
乳化与乳液稳定性:界面性质的作用
Adv Colloid Interface Sci. 2021 Feb;288:102344. doi: 10.1016/j.cis.2020.102344. Epub 2020 Dec 14.
4
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J Colloid Interface Sci. 2020 Oct 15;578:629-640. doi: 10.1016/j.jcis.2020.06.019. Epub 2020 Jun 7.
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Microfluidic production of size-tunable hexadecane-in-water emulsions: Effect of droplet size on destabilization of two-dimensional emulsions due to partial coalescence.微流控法制备十六烷/水尺寸可调乳液:液滴尺寸对二维乳液部分聚并失稳的影响。
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