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含吡啶基-中离子卡宾配体的铬(0)、钼(0)和钨(0)羰基配合物对一氧化碳进行开/关(光)切换结合的机理与动力学研究

Mechanistic and Kinetic Investigations of ON/OFF (Photo)Switchable Binding of Carbon Monoxide by Chromium(0), Molybdenum(0) and Tungsten(0) Carbonyl Complexes with a Pyridyl-Mesoionic Carbene Ligand.

作者信息

Boden Pit J, Di Martino-Fumo Patrick, Bens Tobias, Steiger Sophie T, Marhöfer Daniel, Niedner-Schatteburg Gereon, Sarkar Biprajit

机构信息

Department of Chemistry and State Research Center Optimas, TU Kaiserslautern, Erwin-Schrödinger-Straße 52, 67663, Kaiserslautern, Germany.

Chair of Inorganic Coordination Chemistry, Institute of Inorganic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569, Stuttgart, Germany.

出版信息

Chemistry. 2022 Sep 12;28(51):e202202543. doi: 10.1002/chem.202202543. Epub 2022 Sep 1.

Abstract

Invited for the cover of this issue are Gereon Niedner-Schatteburg, Biprajit Sarkar and co-worker at TU Kaiserslautern and the University of Stuttgart. The image depicts the selective dissociation of an axial CO from a metal complex. Read the full text of the article at 10.1002/chem.202201038.

摘要

本期封面受邀人物是凯撒斯劳滕工业大学和斯图加特大学的格伦·尼德纳-沙滕堡、比普拉吉特·萨卡尔及其同事。图片展示了轴向一氧化碳从金属络合物中的选择性解离。可在10.1002/chem.202201038阅读该文章全文。

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