两全其美：结合金属离子配合物（MICs）和弱配位阴离子（WCAs）的力量以生成具有π-接受配体的稳定且结晶的Cr-四羰基配合物。
The Best of Both Worlds: Combining the Power of MICs and WCAs To Generate Stable and Crystalline Cr -Tetracarbonyl Complexes with π-Accepting Ligands.
作者信息
Bens Tobias, Walter Robert R M, Beerhues Julia, Schmitt Manuel, Krossing Ingo, Sarkar Biprajit
机构信息
Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569, Stuttgart, Germany.
Current address: Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology (BIST), Av. Països Catalans 16, 43007, Tarragona, Spain.
出版信息
Chemistry. 2023 Sep 6;29(50):e202302317. doi: 10.1002/chem.202302317. Epub 2023 Aug 8.
Invited for the cover of this issue are Biprajit Sarkar and co-workers at the University of Stuttgart and University of Freiburg. In the image, the solar flare represents the non-innocence (fluorine-specific interactions) of the counterion, and the black hole at the metal center illustrates the oxidation/electron deficiency of the Cr-center, while the electron "gets lost" in the space (oxidation agent). Read the full text of the article at 10.1002/chem.202301205.
本期封面文章的受邀作者是斯图加特大学和弗莱堡大学的比普拉吉特·萨卡尔及其同事。在图中，太阳耀斑代表抗衡离子的非无害性（氟特异性相互作用），金属中心的黑洞说明了铬中心的氧化/电子缺乏，而电子在空间中“丢失”（氧化剂）。可在10.1002/chem.202301205阅读该文章的全文。
Zotero 插件