In-Well Degassing of Monitoring Wells Completed in Gas-Charged Aquifers.

Total dissolved gas pressure (P ) measurements are useful to measure accurate in situ dissolved gas concentrations in groundwater, but challenged by in-well degassing. Although in-well degassing has been widely observed, its cause(s) are not clear. We investigated the mechanism(s) by which gas-charged groundwater in a recently pumped well becomes degassed. Vertical P and dissolved gas concentration profiles were monitored in the standing water column (SWC) of a groundwater well screened in a gas-charged aquifer for 7 days before and 15 days after pumping. Prior to pumping, P values remained relatively constant and below calculated bubbling pressure (P ) at all depths. In contrast, significant increases in P were observed at all depths after pumping was initiated, as fresh groundwater with elevated in situ P values was pumped through the well screen. After pumping ceased, P values decreased to below P at all depths over the 15-day post-pumping period, indicating well degassing was active over this time frame. Vertical profiles of estimated dissolved gas concentrations before and after pumping provided insight into the mechanism(s) by which in-well degassing occurred in the SWC. During both monitoring periods, downward mixing of dominant atmospheric and/or tracer gases, and upwards mixing of dominant groundwater gases were observed in the SWC. The key mechanisms responsible for in-well degassing were (i) bubble exsolution when P exceeded P as gas-charged well water moves upwards in the SWC during recovery (i.e., hydraulic gradient driven convection), (ii) microadvection caused by the upward migration of bubbles under buoyancy, and (iii) long-term, thermally driven vertical convection.