Super-Reversible CuF Cathodes Enabled by Cu -Coordinated Alginate.

Copper fluoride (CuF ) has the highest energy density among all metal fluoride cathodes owing to its high theoretical potential (3.55 V) and high capacity (528 mAh g ). However, CuF  can only survive for less than five cycles, mainly due to serious Cu-ion dissolution during charge/discharge cycles. Herein, copper dissolution is successfully suppressed by forming Cu -coordinated sodium alginate (Cu-SA) on the surface of CuF  particles during the electrode fabrication process, by using water as a slurry solvent and sodium alginate (SA) as a binder. The trace dissolved Cu in water from CuF  can in situ cross-link with SA binder forming a conformal Cu-SA layer on CuF  surface. After water evaporation during the electrode dry process, the Cu-SA layer is Li-ion conductor but Cu insulator, which can effectively suppress the dissolution of Cu-ions in the organic 4 m LiClO /ethylene carbonate/propylene carbonate electrolyte, enhancing the reversibility of CuF . CuF  electrode with SA binder delivers a reversible capacity of 420.4 mAh g  after 50 cycles at 0.05 C, reaching an energy density of 1009.1 Wh kg . Cu cross-link polymer coating on CuF  opens the door for stabilizing the high-energy and low-cost CuF  cathode for next-generation Li-ion batteries.