• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

荧光锌双水杨醛缩乙二胺配合物在系统结构修饰后发射效率和波长的变化

Variation of the Emission Efficiency and Wavelength from Fluorescent Zinc Salen Complexes upon Systematic Structural Modifications.

作者信息

Kurahashi Takuya

机构信息

Department of Nutrition Science, Faculty of Nursing and Nutrition, University of Nagasaki, Siebold, Manabino, Nagayo, Nagasaki 851-2195, Japan.

出版信息

ACS Omega. 2022 Aug 17;7(34):30642-30654. doi: 10.1021/acsomega.2c04714. eCollection 2022 Aug 30.

DOI:10.1021/acsomega.2c04714
PMID:36061697
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9435038/
Abstract

Understanding the photophysical properties of metal salen complexes is not straightforward because the emission efficiency is altered irregularly upon structural modifications. The present study prepared zinc salen complexes with systematic structural variations to pinpoint critical factors to determine the emission efficiency. One of the important experimental observations is the regiochemistry of a phenolate substituent affecting emission efficiency from a salicylidene fluorophore, which is nicely assigned as arising from the photoexcited electronic structure of metal salen complexes. Another significant finding is the thermal fluctuation of a salen ligand arising from the mismatched ligand-metal interaction, which has a significant impact on fluorescence lifetime. The present study sheds light on hidden factors that alter photophysical properties of a metal salen complex, which provide valuable insights into designing new photoactive salen ligands.

摘要

理解金属双水杨醛缩邻苯二胺配合物的光物理性质并非易事，因为结构修饰会不规则地改变其发射效率。本研究制备了具有系统结构变化的锌双水杨醛缩邻苯二胺配合物，以确定决定发射效率的关键因素。重要的实验观察结果之一是酚盐取代基的区域化学影响水杨醛荧光团的发射效率，这很好地归因于金属双水杨醛缩邻苯二胺配合物的光激发电子结构。另一个重要发现是由于配体 - 金属相互作用不匹配而导致的双水杨醛缩邻苯二胺配体的热波动，这对荧光寿命有重大影响。本研究揭示了改变金属双水杨醛缩邻苯二胺配合物光物理性质的隐藏因素，为设计新型光活性双水杨醛缩邻苯二胺配体提供了有价值的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/49cce649b9cf/ao2c04714_0018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/7dd5f198a566/ao2c04714_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/e49a6f3a7ead/ao2c04714_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/740eeb16d637/ao2c04714_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/cb9559e8feb0/ao2c04714_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/3df33d8c9c1b/ao2c04714_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/6d16f40f667f/ao2c04714_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/9fb9985d67cc/ao2c04714_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/db747214e441/ao2c04714_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/732704430729/ao2c04714_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/5f691dac63e6/ao2c04714_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/552deff038e6/ao2c04714_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/3faddfd21809/ao2c04714_0013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/0ad8a13b3c50/ao2c04714_0014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/96a8c51f2df2/ao2c04714_0015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/8f6de1a1842a/ao2c04714_0016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/d90a4b5cebd6/ao2c04714_0017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/49cce649b9cf/ao2c04714_0018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/7dd5f198a566/ao2c04714_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/e49a6f3a7ead/ao2c04714_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/740eeb16d637/ao2c04714_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/cb9559e8feb0/ao2c04714_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/3df33d8c9c1b/ao2c04714_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/6d16f40f667f/ao2c04714_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/9fb9985d67cc/ao2c04714_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/db747214e441/ao2c04714_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/732704430729/ao2c04714_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/5f691dac63e6/ao2c04714_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/552deff038e6/ao2c04714_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/3faddfd21809/ao2c04714_0013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/0ad8a13b3c50/ao2c04714_0014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/96a8c51f2df2/ao2c04714_0015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/8f6de1a1842a/ao2c04714_0016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/d90a4b5cebd6/ao2c04714_0017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ea4/9435038/49cce649b9cf/ao2c04714_0018.jpg

相似文献

1
Variation of the Emission Efficiency and Wavelength from Fluorescent Zinc Salen Complexes upon Systematic Structural Modifications.荧光锌双水杨醛缩乙二胺配合物在系统结构修饰后发射效率和波长的变化
ACS Omega. 2022 Aug 17;7(34):30642-30654. doi: 10.1021/acsomega.2c04714. eCollection 2022 Aug 30.
2
Strong Fluorescent Lanthanide Salen Complexes: Photophysical Properties, Excited-State Dynamics, and Bioimaging.强荧光镧系 Salen 配合物：光物理性质、激发态动力学和生物成像。
Inorg Chem. 2019 Feb 4;58(3):1806-1814. doi: 10.1021/acs.inorgchem.8b02376. Epub 2018 Dec 21.
3
A theoretical investigation into the luminescent properties of d8-transition-metal complexes with tetradentate Schiff base ligands.关于具有四齿席夫碱配体的d8-过渡金属配合物发光性质的理论研究。
Chemistry. 2014 May 19;20(21):6433-43. doi: 10.1002/chem.201304375. Epub 2014 Apr 8.
4
cis-2,5-Diaminobicyclo[2.2.2]octane, a New Chiral Scaffold for Asymmetric Catalysis.顺-2,5-二氨基双环[2.2.2]辛烷，一种用于不对称催化的新手性骨架。
Acc Chem Res. 2016 Sep 20;49(9):1825-34. doi: 10.1021/acs.accounts.6b00286. Epub 2016 Aug 9.
5
Synthesis and properties of salen-aluminum complexes as a novel class of color-tunable luminophores.新型颜色可调发光体——水杨醛缩邻氨基苯酚铝配合物的合成与性质
Chemistry. 2009 Jun 22;15(26):6478-87. doi: 10.1002/chem.200900137.
6
Soluble monometallic salen complexes derived from O-functionalised diamines as metalloligands for the synthesis of heterobimetallic complexes.由 O-官能化二胺衍生的可溶性单金属 salen 配合物作为金属配合物合成的金属配体。
Dalton Trans. 2010 May 7;39(17):4090-106. doi: 10.1039/b920706f. Epub 2010 Mar 12.
7
Tuning ligand electronics and peripheral substitution on cobalt salen complexes: structure and polymerisation activity.调节钴席夫碱配合物的配体电子和外围取代基：结构和聚合活性。
Dalton Trans. 2014 Mar 21;43(11):4295-304. doi: 10.1039/c3dt51846a.
8
Aluminum salen complexes and tetrabutylammonium salts: a binary catalytic system for production of polycarbonates from CO2 and cyclohexene oxide.铝-双水杨醛缩乙二胺配合物与四丁基铵盐：一种由二氧化碳和环氧环己烷制备聚碳酸酯的二元催化体系。
Inorg Chem. 2005 Mar 7;44(5):1433-42. doi: 10.1021/ic048508g.
9
Computational design of two-photon fluorescent probes for a zinc ion based on a Salen ligand.基于席夫碱配体的锌离子双光子荧光探针的计算设计。
Inorg Chem. 2013 May 20;52(10):5702-13. doi: 10.1021/ic3022062. Epub 2013 May 8.
10
Unique ligand-radical character of an activated cobalt salen catalyst that is generated by aerobic oxidation of a cobalt(II) salen complex.钴席夫碱配合物在有氧氧化条件下生成的具有独特的配位自由基特性的钴激活催化剂。
Inorg Chem. 2013 Apr 1;52(7):3908-19. doi: 10.1021/ic302677f. Epub 2013 Mar 21.

引用本文的文献

1
Detection of VOCs and Biogenic Amines Through Luminescent Zn-Salen Complex-Tethered Pyrenyl Arms.通过发光的锌-萨伦配合物连接的芘基臂检测挥发性有机化合物和生物胺。
Molecules. 2024 Dec 8;29(23):5796. doi: 10.3390/molecules29235796.
2
A Zinc(II) Schiff Base Complex as Fluorescent Chemosensor for the Selective and Sensitive Detection of Copper(II) in Aqueous Solution.一种锌(II)席夫碱配合物作为荧光化学传感器，用于在水溶液中选择性和灵敏地检测铜(II)。
Sensors (Basel). 2023 Apr 12;23(8):3925. doi: 10.3390/s23083925.

本文引用的文献

1
Asymmetric Catalysis Using Chiral Salen-Metal Complexes: Recent Advances.手性水杨醛亚胺-金属配合物的不对称催化：最新进展。
Chem Rev. 2019 Aug 28;119(16):9381-9426. doi: 10.1021/acs.chemrev.9b00074. Epub 2019 Jun 11.
2
Salen-indium/triarylborane triads: synthesis and ratiometric emission-colour changes by fluoride ion binding.水杨醛缩铟/三芳基硼三元体系：通过氟离子结合的合成及比率发射颜色变化
Dalton Trans. 2018 Apr 17;47(15):5310-5317. doi: 10.1039/c8dt00153g.
3
Drastic Redox Shift and Electronic Structural Changes of a Manganese(III)-Salen Oxidation Catalyst upon Reaction with Hydroxide and Cyanide Ion.
Inorg Chem. 2018 Feb 5;57(3):1066-1078. doi: 10.1021/acs.inorgchem.7b02474. Epub 2018 Jan 11.
4
Aggregates of Defined Stereochemical Scaffolds: A Study in Solution of a Zinc(II) Schiff Base Complex Derived from the Enantiopure trans-1,2-Cyclopentanediamine.特定立体化学支架的聚集体：源自对映体纯反式-1,2-环戊二胺的锌（II）席夫碱配合物的溶液研究
Inorg Chem. 2017 Nov 20;56(22):14206-14213. doi: 10.1021/acs.inorgchem.7b02341. Epub 2017 Nov 7.
5
A Schiff base platform: structures, sensing of Zn(ii) and PPi in aqueous medium and anticancer activity.希夫碱平台：结构、在水介质中对 Zn(ii)和 PPi 的传感及抗癌活性。
Dalton Trans. 2017 Jul 25;46(29):9498-9510. doi: 10.1039/c7dt01932g.
6
Synthesis and Dual-Emission Feature of Salen-Al/Triarylborane Dyads.Salen-Al/三芳基硼二元化合物的合成与双发射特性
Inorg Chem. 2017 Jun 5;56(11):6039-6043. doi: 10.1021/acs.inorgchem.7b00768. Epub 2017 May 24.
7
Bis-Zn salphen complexes bearing pyridyl functionalized ligands for efficient organic light-emitting diodes (OLEDs).用于高效有机发光二极管（OLED）的带有吡啶基官能化配体的双锌双水杨醛缩邻苯二胺配合物。
Dalton Trans. 2017 May 9;46(18):6098-6110. doi: 10.1039/c7dt00905d.
8
Intriguing Indium-salen Complexes as Multicolor Luminophores.有趣的铟-萨伦配合物作为多色发光体。
Inorg Chem. 2017 Mar 6;56(5):2621-2626. doi: 10.1021/acs.inorgchem.6b02797. Epub 2017 Feb 13.
9
Ligand-centred oxidative chemistry in sterically hindered salen complexes: an interesting case with nickel.空间位阻型萨伦配合物中以配体为中心的氧化化学：镍的一个有趣例子。
Dalton Trans. 2016 Jul 5;45(27):10866-77. doi: 10.1039/c6dt00942e.
10
A highly selective, sensitive and reversible fluorescence chemosensor for Zn(2+) and its cell viability.一种用于锌离子（Zn(2+)）的高选择性、高灵敏度且可逆的荧光化学传感器及其细胞活力
Dalton Trans. 2016 Mar 7;45(9):3927-35. doi: 10.1039/c5dt04945h.