Guo Jining, Zhang Yuecheng, Zavabeti Ali, Chen Kaifei, Guo Yalou, Hu Guoping, Fan Xiaolei, Li Gang Kevin
Department of Chemical Engineering, The University of Melbourne, Parkville, Vic, 3010, Australia.
Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou, Jiangxi, 341000, China.
Nat Commun. 2022 Sep 6;13(1):5046. doi: 10.1038/s41467-022-32652-y.
Green hydrogen produced by water splitting using renewable energy is the most promising energy carrier of the low-carbon economy. However, the geographic mismatch between renewables distribution and freshwater availability poses a significant challenge to its production. Here, we demonstrate a method of direct hydrogen production from the air, namely, in situ capture of freshwater from the atmosphere using hygroscopic electrolyte and electrolysis powered by solar or wind with a current density up to 574 mA cm. A prototype of such has been established and operated for 12 consecutive days with a stable performance at a Faradaic efficiency around 95%. This so-called direct air electrolysis (DAE) module can work under a bone-dry environment with a relative humidity of 4%, overcoming water supply issues and producing green hydrogen sustainably with minimal impact to the environment. The DAE modules can be easily scaled to provide hydrogen to remote, (semi-) arid, and scattered areas.
利用可再生能源通过水分解产生的绿色氢气是低碳经济中最具前景的能量载体。然而,可再生能源分布与淡水资源可利用性之间的地理不匹配对其生产构成了重大挑战。在此,我们展示了一种从空气中直接制氢的方法,即使用吸湿电解质从大气中就地捕获淡水,并利用太阳能或风能进行电解,电流密度高达574 mA/cm²。已经建立了这样一个原型,并连续运行了12天,在约95%的法拉第效率下性能稳定。这种所谓的直接空气电解(DAE)模块可以在相对湿度为4%的极度干燥环境下工作,克服了供水问题,并以对环境影响最小的方式可持续地生产绿色氢气。DAE模块可以轻松扩大规模,为偏远、(半)干旱和分散地区提供氢气。