Materials Genome Institute and Shanghai Engineering Research Center of Organ Repair, Shanghai University, Shanghai, 200444, China.
Division of Biological Inorganic Chemistry, State Key Laboratory of Rare Earth Resource Utilization, Laboratory of Chemical Biology, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, China.
Angew Chem Int Ed Engl. 2022 Nov 21;61(47):e202211822. doi: 10.1002/anie.202211822. Epub 2022 Oct 12.
Chiral materials related to circularly polarized luminescence (CPL) make up a rapidly developing new field that has broad application prospects in optoelectronic devices, selective recognition, biomedicine, and other fields. Biofunctional chiral materials are also attracting increasing attention because of their unique biocompatibility, chiral recognition, and coding. However, there has been little discussion on biomolecule-based CPL till now. In this Review, the latest progress in CPL materials related with biomolecules are reviewed, including the chiral construction from molecular level to giant microstructure, as well as their emerging applications. In addition, we discuss the challenges and prospects of bio-based CPL materials, hoping this work will provide new perspectives and insights for more related research.
手性材料与圆偏振发光(CPL)有关,构成了一个快速发展的新领域,在光电设备、选择性识别、生物医药等领域具有广阔的应用前景。生物功能手性材料也因其独特的生物相容性、手性识别和编码而引起越来越多的关注。然而,到目前为止,关于基于生物分子的 CPL 的讨论还很少。在这篇综述中,我们回顾了与生物分子相关的 CPL 材料的最新进展,包括从分子水平到巨微结构的手性构建,以及它们新兴的应用。此外,我们还讨论了基于生物的 CPL 材料所面临的挑战和前景,希望这项工作能为更多相关研究提供新的视角和见解。