Zhou Chengkai, Chang Weixing, Liu Lingyan, Li Jing
The State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, National Engineering Research Center of Pesticide, Nankai University, Tianjin 300071, China.
National Engineering Research Center of Pesticide, Nankai University, Tianjin 300071, China.
Polymers (Basel). 2024 Jul 27;16(15):2140. doi: 10.3390/polym16152140.
Circularly polarized luminescence (CPL) materials have been widely used in the fields of bioimaging, optoelectronic devices, and optical communications. The supramolecular interaction, involving harnessing non-covalent interactions between host and guest molecules to control their arrangements and assemblies, represents an advanced approach for facilitating the development of CPL materials and finely constructing and tuning the desired CPL properties. Cyclodextrins () are cyclic natural polysaccharides, which have also been ubiquitous in various fields such as molecular recognition, drug encapsulation, and catalyst separation. By adjusting the interactions between and guest molecules precisely, composite materials with CPL properties can be facilely generated. This review aims to outline the design strategies and performance of -based CPL materials comprehensively and provides a detailed illustration of the interactions between host and guest molecules.
圆偏振发光(CPL)材料已广泛应用于生物成像、光电器件和光通信等领域。超分子相互作用涉及利用主体分子和客体分子之间的非共价相互作用来控制它们的排列和组装,是促进CPL材料发展以及精细构建和调节所需CPL特性的一种先进方法。环糊精(CDs)是环状天然多糖,在分子识别、药物包封和催化剂分离等各个领域也普遍存在。通过精确调节CDs与客体分子之间的相互作用,可以轻松制备具有CPL特性的复合材料。本综述旨在全面概述基于CDs的CPL材料的设计策略和性能,并详细阐述主体分子与客体分子之间的相互作用。