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用于高性能不对称超级电容器的CoSe/CoO-CNTs/NF复合电极的简便合成

Facile Synthesis of CoSe/CoO-CNTs/NF Composite Electrode for High-Performance Asymmetric Supercapacitor.

作者信息

Wang Ying, Zheng Xiang, Cao Xianjun, Yang Chengtao, Zhao Qiang, Zhang Yongqi, Xia Xinhui

机构信息

Yangtze Delta Region Institute (Huzhou), University of Electronic Science and Technology of China, Huzhou 313001, China.

School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China.

出版信息

Materials (Basel). 2022 Aug 24;15(17):5841. doi: 10.3390/ma15175841.

Abstract

Electrode materials are key factors for supercapacitors to endow them with excellent electrochemical properties. Here, a novel hybrid structure of a CoSe/CoO-CNTs binder free composite electrode on nickel foam was prepared via a facile flame method, followed by an electrodeposition process. Benefitting from the synergetic effects of the multicomponent (with low resistances of 1.542 Ω cm and a moderate mesoporous size of 3.12 nm) and the enlarged specific surface area of the composite material (77.4 m g), the CoSe/CoO-CNTs composite electrode delivers a high specific capacitance of 2906 F g at 5 mV s with an excellent rate stability. The fabricated CoSe/Co3O4-CNTs/NF//AC ASC exhibits a high energy density of 43.4 Wh kg at 0.8 kW kg and a long cycle life (92.7% capacitance retention after 10,000 cycles).

摘要

电极材料是超级电容器赋予其优异电化学性能的关键因素。在此,通过简便的火焰法制备了一种新型的泡沫镍上的CoSe/CoO-CNTs无粘结剂复合电极的混合结构,随后进行电沉积过程。受益于多组分的协同效应(具有1.542Ω·cm的低电阻和3.12nm的适中中孔尺寸)以及复合材料增大的比表面积(77.4m²/g),CoSe/CoO-CNTs复合电极在5mV/s时具有2906F/g的高比电容以及优异的倍率稳定性。所制备的CoSe/Co₃O₄-CNTs/NF//AC不对称超级电容器在0.8kW/kg时具有43.4Wh/kg的高能量密度以及长循环寿命(10000次循环后电容保持率为92.7%)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e144/9457315/543106d016c3/materials-15-05841-sch001.jpg

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