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氯离子循环侵蚀作用下混凝土中氯离子传输的数值模拟

Numerical Modeling of Chloride Transport in Concrete under Cyclic Exposure to Chloride.

作者信息

Lee Jae-Min, Hong Sung In, Yang Hee Jun, Jung Dong-Hyuk

机构信息

Department of Civil Engineering, Kumon National Institute of Technology, Daehak-ro 61, Gumi 39177, Korea.

Environment and Energy Research Team, Hyundai Steel Company, Bukbusaneop-ro 1480, Dangjin 31719, Korea.

出版信息

Materials (Basel). 2022 Aug 29;15(17):5966. doi: 10.3390/ma15175966.

Abstract

Concrete structures under cyclic exposure to chlorides entail a higher risk of embedded steel corrosion along with accelerated ionic ingress from the environment. This study proposes a coupled transport model considering moisture and chloride distribution in concrete to investigate the influence of a cyclic exposure condition on chloride penetration. In this model, pore size distribution to quantify the effective pore space for moisture and chloride mobilizations was determined to establish the governing equation for chloride transport through non-saturated concrete. From the simulation results, the rate of chloride penetration increases with decreasing ambient humidity levels due to the enhanced chloride convection. Finally, the coupled transport model was verified by comparing in-situ data, showing reasonable correlations with 0.83 and 0.93 of determinant coefficients for 22 and 44 years of exposure, respectively, while those obtained from LIFE 365 were much lower.

摘要

在氯化物循环作用下的混凝土结构,会使埋入的钢筋面临更高的腐蚀风险,同时环境中的离子侵入也会加速。本研究提出了一个考虑混凝土中水分和氯化物分布的耦合传输模型,以研究循环暴露条件对氯化物渗透的影响。在该模型中,确定了用于量化水分和氯化物迁移有效孔隙空间的孔径分布,从而建立了氯化物在非饱和混凝土中传输的控制方程。从模拟结果来看,由于氯化物对流增强,氯化物渗透速率随环境湿度水平降低而增加。最后,通过与现场数据比较验证了该耦合传输模型,结果显示对于22年和44年暴露时间,决定系数分别为0.83和0.93,具有合理的相关性,而从LIFE 365获得的决定系数则低得多。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc18/9457048/05fb53bff232/materials-15-05966-g001.jpg

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