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碱激发矿渣-粉煤灰胶凝材料的强度特性及微观结构分析

Strength Characteristics and Microstructure Analysis of Alkali-Activated Slag-Fly Ash Cementitious Material.

作者信息

Zhu Chenhui, Wan Yuanyuan, Wang Lei, Ye Yuchen, Yu Houjun, Yang Jie

机构信息

School of Transportation and Civil Engineering, Nantong University, Nantong 226019, China.

Nantong Construction Engineering Quality Testing Center, Nantong 226019, China.

出版信息

Materials (Basel). 2022 Sep 5;15(17):6169. doi: 10.3390/ma15176169.

Abstract

Modifying the admixture of alkali-activated cementitious materials using components such as fly ash and fine sand may reduce CO emissions and conserve natural resources and energy. This study adopted strength testing, scanning electron microscopy, and mercury intrusion porosimetry to investigate the influence of different admixtures on the compressive strength and flexural strength of alkali slag cementing materials and the microstructure characteristics of hardened slurry under the action of load. The flexural strength of alkali slag cement slurry and mortar was reduced by replacing slag powder with fly ash. Content of fine sand less than 20% had little effect on the strength of alkali slag cement mortar; however, when the content of fine sand exceeded 30%, the strength decreased significantly. The hydration degree at 3 d was large, and the density of slurry increased with the extension of age. Increased fly ash or fine sand content decreased the density of the slurry, and increased fly ash resulted in a large number of unhydrated fly ash particles in the cementitious materials. Addition of fine sand resulted in a large number of microcracks in the slurry, which gradually decreased with the extension of hydration age.

摘要

使用粉煤灰和细砂等成分来改变碱激活胶凝材料的混合料,可能会减少二氧化碳排放,并节约自然资源和能源。本研究采用强度测试、扫描电子显微镜和压汞法,来研究不同掺合料对碱矿渣胶凝材料抗压强度和抗折强度的影响,以及在荷载作用下硬化浆体的微观结构特征。用粉煤灰替代矿渣粉会降低碱矿渣水泥浆体和砂浆的抗折强度。细砂含量小于20%时,对碱矿渣水泥砂浆强度影响不大;然而,当细砂含量超过30%时,强度显著下降。3天时水化程度较大,浆体密度随龄期延长而增加。粉煤灰或细砂含量增加会降低浆体密度,粉煤灰增加会导致胶凝材料中有大量未水化的粉煤灰颗粒。添加细砂会导致浆体中出现大量微裂纹,这些微裂纹会随着水化龄期的延长而逐渐减少。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5068/9458206/29c9dfd7662a/materials-15-06169-g001.jpg

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