Ru Shaofeng, Zhao Can, Yang Songmei, Liang Dong
Mechanical and Electrical Engineering College, Hainan University, Haikou 570228, China.
Polymers (Basel). 2022 Aug 25;14(17):3488. doi: 10.3390/polym14173488.
Coir-fiber-reinforced epoxy resin composites are an environmentally friendly material, and the use of coir fibers improves the mechanical properties of epoxy resin. In order to improve the interfacial adhesion between coir fibers and the epoxy resin matrix, microwave treatment, alkali treatment, acetic anhydride modification, 3-aminopropyltriethoxysilane modification and their reasonable combination method treatments were carried out on coir fibers, respectively. Scanning electron microscopy (SEM), Fourier transform-infrared (FTIR) and X-ray diffraction (XRD) were used to analyze the effects of the different treatments on the characteristics of the coir fibers, and single-fiber pullout tests were performed on the pullout specimens made from the above coir fibers. The results calculated by the proposed estimation method show that the combination method of alkali treatment and 3-aminopropyltriethoxysilane surface modification could better enhance the interfacial bonding ability between coir fibers and epoxy resin with an interfacial shear strength and pullout energy of 6.728 MPa and 40.237 N·mm, respectively. The principal analysis shows that the method can form both mechanical interlocking and chemical bonds at the interface to enhance the interfacial bonding ability. This study provides a more suitable method for improving the interfacial properties of coir-fiber-reinforced epoxy resin composites and has implications for the study of natural fiber composites.
椰壳纤维增强环氧树脂复合材料是一种环保材料,椰壳纤维的使用改善了环氧树脂的力学性能。为了提高椰壳纤维与环氧树脂基体之间的界面粘结力,分别对椰壳纤维进行了微波处理、碱处理、乙酸酐改性、3-氨丙基三乙氧基硅烷改性及其合理的组合方法处理。采用扫描电子显微镜(SEM)、傅里叶变换红外光谱(FTIR)和X射线衍射(XRD)分析不同处理对椰壳纤维特性的影响,并对由上述椰壳纤维制成的拔出试样进行单纤维拔出试验。通过所提出的估算方法计算得到的结果表明,碱处理与3-氨丙基三乙氧基硅烷表面改性的组合方法能够更好地增强椰壳纤维与环氧树脂之间的界面粘结能力,界面剪切强度和拔出能量分别为6.728MPa和40.237N·mm。主成分分析表明,该方法能够在界面处形成机械互锁和化学键,从而增强界面粘结能力。本研究为改善椰壳纤维增强环氧树脂复合材料的界面性能提供了一种更合适的方法,对天然纤维复合材料的研究具有重要意义。