Shao Zhaoqun, Zhu Min, Liang Tianxi, Wu Fei, Xu Zijian, Yang Yang, Liu Yilong
College of Nuclear Science and Technology, Naval University of Engineering, Wuhan 430033, China.
Polymers (Basel). 2022 Sep 1;14(17):3606. doi: 10.3390/polym14173606.
The mechanical properties of silicone foam will degrade when exposed to environmental loads such as temperature and pressure for a long time. In recent years, the variation law of the stress-strain response of silicone foam during the aging process has received more and more attention, but there are few works that quantitatively analyze the variation of the stress-strain response. In this work, we quantitatively analyzed the variation law of the stress-strain response of silicone foam during aging by the constitutive model. Firstly, the accelerated aging test of silicone rubber foam under long-term compressive strain was carried out, and its compression set, stress relaxation and strain stress curves of different aging degrees were obtained. Further, degenerate trajectory equations for the compression set and stress-relaxation were obtained. In addition, the hyper-foam constitutive model was obtained by fitting stress-strain curves, and the changes in the model parameters after aging were studied. The results show that the compressed set and stress-relaxation are exponential functions of time, while different to existing research findings, we found that the stress-strain curves do not change monotonically with increasing time, which first softens, then hardens, and finally softens. Additionally, to better understand the changing trend of the stress-strain response, the correlation between the stress-strain curve and the compression set and stress-relaxation was discussed qualitatively. Finally, in the stage of monotonic change of the stress-strain curve, the exponential function of the model parameters with the increase of aging time was obtained.
硅橡胶泡沫材料在长期承受温度和压力等环境载荷作用时,其力学性能会发生退化。近年来,硅橡胶泡沫材料在老化过程中的应力 - 应变响应变化规律受到了越来越多的关注,但定量分析应力 - 应变响应变化的研究较少。在本研究中,我们通过本构模型定量分析了硅橡胶泡沫材料在老化过程中的应力 - 应变响应变化规律。首先,对硅橡胶泡沫材料进行了长期压缩应变下的加速老化试验,得到了不同老化程度下的压缩永久变形、应力松弛以及应变 - 应力曲线。进一步地,得到了压缩永久变形和应力松弛的退化轨迹方程。此外,通过拟合应力 - 应变曲线得到了超泡沫本构模型,并研究了老化后模型参数的变化。结果表明,压缩永久变形和应力松弛是时间的指数函数,而与现有研究结果不同的是,我们发现应力 - 应变曲线并非随时间单调变化,而是先软化,再硬化,最后又软化。另外,为了更好地理解应力 - 应变响应的变化趋势,定性地讨论了应力 - 应变曲线与压缩永久变形和应力松弛之间的相关性。最后,在应力 - 应变曲线单调变化阶段,得到了模型参数随老化时间增加的指数函数关系。