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溶解于水中的氙和氪形成纳米液滴:无纳米气泡的证据。

Xenon and Krypton Dissolved in Water Form Nanoblobs: No Evidence for Nanobubbles.

作者信息

Jaramillo-Granada Angela M, Reyes-Figueroa A D, Ruiz-Suárez J C

机构信息

Centro de Investigación y de Estudios Avanzados-Monterrey, Parque de Investigación e Innovación Tecnológica, 66600 Nuevo León, Mexico.

Centro de Investigación en Matemáticas Unidad Monterrey, Av. Alianza Centro No. 502, PIIT, Apodaca, 66628 Nuevo León, Mexico.

出版信息

Phys Rev Lett. 2022 Aug 26;129(9):094501. doi: 10.1103/PhysRevLett.129.094501.

Abstract

We demonstrate, experimentally and by molecular dynamics simulations, that krypton and xenon form nanostructured water-gas domains. High pressure was applied to force the inert gases to dissolve in water following Henry's law, then the liquid was depressurized, centrifuged, and inspected by dynamic light scattering. The observed objects have similar sizes and electrical properties to nanobubbles, but we found that they have fairly neutral buoyancy even at high gravitational fields. We posit that the formed nano objects are not bubbles but blobs, unique structures conceived as clathrate-hydrate precursors, thus resolving the so-called Laplace pressure bubble catastrophe.

摘要

我们通过实验和分子动力学模拟证明,氪和氙会形成纳米结构的水气域。施加高压以使惰性气体按照亨利定律溶解于水中,然后对液体进行减压、离心,并通过动态光散射进行检测。观察到的物体在尺寸和电学性质上与纳米气泡相似,但我们发现即使在高重力场下它们也具有相当中性的浮力。我们认为形成的纳米物体不是气泡而是液滴,即一种被认为是笼形水合物前体的独特结构,从而解决了所谓的拉普拉斯压力气泡灾难。

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