Influence of layer thickness on the power conversion efficiency of tin halide-based planar heterojunction solar cells.

In recent years, perovskite-based solar cell technologies have sparked much interest. Organic-inorganic halide perovskites (OIHPs) are a type of perovskite that has shown promise in various optoelectronic applications. The power conversion efficiency (PCE) of organic-inorganic perovskite materials is improving with new materials development. However, inorganic materials studied in labs have limited PCE. Lead-free tin halide CHNHSnX shows good PCE. In this work, we study the electrical characteristics of tin halide as a perovskite absorbing layer in planar heterojunction solar cells with the help of GPVDM solar cell simulation software. A comparative study of power conversion efficiency has been done for tin halide of chloride, bromide, and iodide. The effect of electron and hole drift-diffusion, carrier continuity equations in position space to represent charge flow within the device, Poisson's equation, and charge carrier recombination has been studied in detail.