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[石家庄市栾城区农田土壤和农作物重金属污染分布特征及风险评估]

[Distribution Characteristics and Risk Assessment of Heavy Metal Pollution in Farmland Soils and Crops in Luancheng, Shijiazhuang City].

作者信息

Meng Xiao-Fei, Guo Jun-Mei, Yang Jun-Xing, Zheng Guo-di, Chen Tong-Bin, Liu Jie

机构信息

Center for Environmental Remediation, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101, China.

University of Chinese Academy of Sciences, Beijing 100049, China.

出版信息

Huan Jing Ke Xue. 2022 Sep 8;43(9):4779-4790. doi: 10.13227/j.hjkx.202109012.

Abstract

In order to explore the distribution characteristics of heavy metal contamination of farmland soil surrounding Luancheng town, Shijiazhuang City, Henan province, the concentrations of As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn in the surface soil and crops were determined and assessed. The principal components were also analyzed for source apportionment. The heavy metal concentrations in crops were further detected, and the non-carcinogenic health risks in the study area were evaluated using the probabilistic risk assessment method, as to provide a theoretical basis for the treatment, prevention, and control of heavy metal pollution in farmland soil in Luancheng. According to the results, (Cd), (Cr), (Cu), (Pb), and (Zn) in the soils were 0.06-1.08, 22.14-473.47, 12.83-150.74, 10.75-577.72, and 62.23-652.78 mg·kg, which exceeded the standard with over-standard rates reaching 1.83%, 1.22%, 0.61%, 0.61%, and 1.22%, respectively. Further, Cd and Pb were transported into crops, in which Cd concentrations exceeded the standard in some corn samples, and Cd and Pb concentrations exceeded the standard in some wheat samples. The total non-carcinogenic health risks (TTHQ) to the human body caused by the consumption of heavy metals in corn grown in the study area were all less than 1, with no obvious negative effects, and TTHQ was higher than 1 in wheat, increasing the likelihood of negative impacts on the human body. With the influence of the distribution of pollution-related enterprises in the industrial zone, heavy metal concentrations were higher in the south, west, and middle directions of the study area. Among them, the study area soil was slightly contaminated by Cd (Level 1). Cd and Hg had a slight potential ecological risk (Level 2), whereas other heavy metals had low potential ecological risk (Level 1). In general, most of the surface cultivated soil was not obviously polluted by heavy metals in the study area. According to the PMF results and survey, we speculated that soil heavy metals mainly came from soil parent material (52.05%), artificial pollution sources (historical sewage irrigation and industrial manufacture) (32.98%), and atmospheric deposition (14.97%). To summarize, the study area should be divided into a priority protection category and safe utilization category. The input of pollution sources should be strictly controlled for the priority protection category, and alternative planting, rotating, and fallow should be implemented for the safe utilization category to reduce the risk of standard-exceeding agricultural products.

摘要

为探究河南省石家庄市栾城镇周边农田土壤重金属污染分布特征,测定并评估了表层土壤和农作物中砷、镉、铬、铜、汞、镍、铅和锌的含量,并对其主成分进行分析以进行源解析。进一步检测了农作物中的重金属含量,采用概率风险评估方法评估了研究区域内的非致癌健康风险,为栾城镇农田土壤重金属污染的治理、预防和控制提供理论依据。结果表明,土壤中镉、铬、铜、铅和锌含量分别为0.06 - 1.08、22.14 - 473.47、12.83 - 150.74、10.75 - 577.72和62.23 - 652.78 mg·kg,均超出标准,超标率分别达1.83%、1.22%、0.61%、0.61%和1.22%。此外,镉和铅向农作物中迁移转化,部分玉米样品中镉含量超标,部分小麦样品中镉和铅含量超标。研究区域内种植的玉米中重金属对人体造成的总非致癌健康风险(TTHQ)均小于1,无明显负面影响,而小麦中的TTHQ高于1,增加了对人体产生负面影响的可能性。受工业园区污染相关企业分布影响,研究区域南部、西部和中部方向的重金属含量较高。其中,研究区域土壤镉轻度污染(Ⅰ级),镉和汞具有轻微潜在生态风险(Ⅱ级),其他重金属具有低潜在生态风险(Ⅰ级)。总体而言,研究区域内大部分表层耕地土壤重金属污染不明显。根据PMF结果及调查推测,土壤重金属主要来源于土壤母质(52.05%)、人为污染源(历史污水灌溉及工业生产)(32.98%)和大气沉降(14.97%)。综上所述,研究区域应划分为优先保护类和安全利用类。对优先保护类应严格控制污染源输入,对安全利用类应实施替代种植、轮作和休耕,以降低农产品超标风险。

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