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从惰性到活性:用于电催化氨氧化反应的银/镍混合物的鸡尾酒式介导作用

From inert to active: a cocktail-like mediation of an Ag/Ni mixture for electrocatalytic ammonia oxidation reaction.

作者信息

Jin Yongzhen, Chen Xin, Wang Jianhui

机构信息

School of Materials Science and Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China.

Key Laboratory of 3D Micro/Nano Fabrication and Characterization of Zhejiang Province, School of Engineering, Westlake University, 18 Shilongshan Road, Hangzhou 310024, China.

出版信息

Chem Commun (Camb). 2022 Sep 22;58(76):10631-10634. doi: 10.1039/d2cc03764e.

Abstract

We report a highly selective electrocatalytic ammonia oxidation reaction (EAOR) induced by handmilling inert powders of silver (NH adsorber) and nickel (OH adsorber and active site). This cocktail-like mediation provides a good model for mechanistic understanding of the EAOR, benefiting the development of effective non-noble metal catalysts for the EAOR.

摘要

我们报道了一种通过手工研磨银(氨吸附剂)和镍(氢氧根吸附剂及活性位点)的惰性粉末诱导的高选择性电催化氨氧化反应(EAOR)。这种类似鸡尾酒的介导方式为EAOR的机理理解提供了一个良好的模型,有利于开发用于EAOR的有效非贵金属催化剂。

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