McHugh Thomas, Newell Charles, Stanley Curt, Johnson Jeff, Roff Douglas
GSI Environmental Inc., Houston, TX, USA.
AECOM, Honolulu, HI, USA.
J Contam Hydrol. 2022 Dec;251:104071. doi: 10.1016/j.jconhyd.2022.104071. Epub 2022 Sep 7.
Our Paper uses two independent methods (carbon dioxide flux and heat flux) to measure the rates of natural source zone depletion (NSZD) at a petroleum release site in Hawaii. The two methods yielded estimates of the NSZD rate that agreed within a factor of 2. We disagree with the technical commentors (Beckett et al., 2022). Specifically, the available data indicate that the observed NSZD is not occurring through a two-stage process of methane generation at the water table followed by methane oxidation in the vadose zone; rather direct aerobic oxidation of LNAPL in the vadose zone is the simplest and most likely explanation for the observed heat generation. In addition, the agreement between the two independent NSZD rate measurement methods and the temporal consistency in the measured heat flux across two field events provides confidence that the NSZD rates presented in the paper are not greatly over or under-estimated.
我们的论文采用了两种独立方法(二氧化碳通量和热通量)来测量夏威夷一个石油泄漏场地的自然源区消耗(NSZD)速率。这两种方法得出的NSZD速率估计值在2倍的范围内相符。我们不同意技术评论者(贝克特等人,2022年)的观点。具体而言,现有数据表明,观察到的NSZD并非通过地下水位处甲烷生成然后在包气带中进行甲烷氧化的两阶段过程发生;相反,包气带中轻非水相液体(LNAPL)的直接好氧氧化是观察到的热量产生的最简单且最有可能的解释。此外,两种独立的NSZD速率测量方法之间的一致性以及两次现场事件中测量热通量的时间一致性,让人相信论文中给出的NSZD速率没有被大幅高估或低估。