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对《夏威夷玄武岩渗流带轻非水相液体源的直接好氧非饱和带零价铁处理》的技术评论,麦克休等人,《危险材料杂志》第235期(2020年)

Technical commentary to: Direct aerobic NSZD of a basalt vadose zone LNAPL source in Hawaii, McHugh et al., JCH #235 (2020).

作者信息

Beckett G D, Thomas Donald, Whittier Robert

机构信息

AQUI-VER, Inc., Park City, UT, United States of America.

University of Hawaii, Manoa, United States of America.

出版信息

J Contam Hydrol. 2022 Dec;251:104070. doi: 10.1016/j.jconhyd.2022.104070. Epub 2022 Sep 6.

Abstract

The subject Paper (McHugh et al., 2020) uses carbon dioxide and net thermal signatures to derive conclusions about the rates of natural source zone depletion (NSZD), as well as the location of residual fuel in the formation. We concur that both data sets are indicators of active fuel biodegradation, however, the simplifications of McHugh et al. render its estimates of NSZD rates uncertain and likely over-estimated. We cannot infer what role this degradation capacity may play in site management because: a) the biodegradation evidence is spatially limited and cannot be linked to LNAPL source zones; b) the LNAPL source zones are so poorly understood that we have no mass constraints or balances; and c) this is a very heterogeneous site, in terms of LNAPL source locations, masses, rates, and related subsurface properties. Consequently, much McHugh et al., 2020 amounts to speculative hypotheses and estimates of NSZD that are unbounded by confirmatory data. Several of the McHugh et al. authors prepared a conceptual site model (CSM) report that can be downloaded from the EPA website: https://www.epa.gov/sites/production/files/201907/documents/red_hill_conceptual_site_model_20190630-redacted.pdf. This CSM report incorporates the conclusions of McHugh et al., 2020 as part of a broader interpretation of a generally safe setting with regard to potential aquifer damages being caused by past and future fuel releases because of the assumed large fuel holding and assimilative capacities. Substantial impacts to the aquifer caused by recent fuel releases (May and November 2021) have contaminated drinking water and affected thousands of base residents. These aquifer impact events serve to highlight the importance of adequate technical detail in evaluations, particularly in complex settings like at the subject site. A partial synopsis of these recent fuel release events can be found at: https://www.hawaiipublicradio.org/local-news/2021-12-21/confused-about-the-timeline-for-the-red-hill-fuel-storage-facility-and-contaminated-water-read-this.

摘要

主题论文(麦克休等人,2020年)利用二氧化碳和净热特征得出关于自然源区耗竭速率(NSZD)以及地层中残留燃料位置的结论。我们同意这两个数据集都是活性燃料生物降解的指标,然而,麦克休等人的简化处理使其对NSZD速率的估计不确定且可能被高估。我们无法推断这种降解能力在场地管理中可能发挥什么作用,原因如下:a)生物降解证据在空间上有限,无法与轻非水相液体(LNAPL)源区联系起来;b)对LNAPL源区了解甚少,以至于我们没有质量限制或平衡;c)就LNAPL源位置、质量、速率和相关地下特性而言,这是一个非常不均匀的场地。因此,麦克休等人2020年的许多内容相当于无确凿数据支持的关于NSZD的推测性假设和估计。麦克休等人的几位作者编写了一份概念性场地模型(CSM)报告,可从美国环境保护局网站下载:https://www.epa.gov/sites/production/files/201907/documents/red_hill_conceptual_site_model_20190630-redacted.pdf。这份CSM报告纳入了麦克休等人2020年的结论,作为对一个总体安全环境的更广泛解释的一部分,该环境涉及过去和未来燃料泄漏可能对含水层造成的潜在损害,这是基于假定的大量燃料储存和同化能力。近期燃料泄漏(2021年5月和11月)对含水层造成的重大影响已污染饮用水并影响了数千名基地居民。这些含水层影响事件凸显了评估中充分技术细节的重要性,尤其是在像主题场地这样的复杂环境中。这些近期燃料泄漏事件的部分概要可在以下网址找到:https://www.hawaiipublicradio.org/local-news/2021-12-21/confused-about-the-timeline-for-the-red-hill-fuel-storage-facility-and-contaminated-water-read-this。

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