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二氧化硅包裹的半导体异质纳米片的金等离子体增强发光

Gold plasmonic enhanced luminescence of silica encapsulated semiconductor hetero-nanoplatelets.

作者信息

Garcia Emilio, Arnold Christophe, Hermier Jean-Pierre, D'Amico Michele

机构信息

Université Paris-Saclay, UVSQ, CNRS, GEMaC 78000 Versailles France

Nexdot 102 Avenue Gaston Roussel 93230 Romainville France

出版信息

Nanoscale Adv. 2021 Jun 18;3(15):4572-4578. doi: 10.1039/d1na00273b. eCollection 2021 Jul 27.

Abstract

Optical properties of nanocrystals have the potential to drive the next generation of optoelectronic devices. However, a number of technological limitations remain to be overcome. Nanocrystals' emission is strongly impacted by the chemical environment and high excitation power. In this paper, we present a preparation route to hybrid core-shell nanoplatelets encapsulated in a gold silica shield. The induced plasmon coupling offers a higher brightness at high power excitation. We also detail the highly increased fluorescence stability offered by the silica-gold-shell protection against photobleaching processes.

摘要

纳米晶体的光学特性有潜力推动下一代光电器件的发展。然而,仍有许多技术限制有待克服。纳米晶体的发射受到化学环境和高激发功率的强烈影响。在本文中,我们提出了一种制备包裹在金硅壳中的混合核壳纳米片的方法。诱导的等离子体耦合在高功率激发下提供了更高的亮度。我们还详细阐述了硅金壳对光漂白过程的保护作用所带来的荧光稳定性的大幅提高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff27/9417742/ca73a9c27869/d1na00273b-f1.jpg

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