Barnett Chris J, Gowenlock Cathren E, Orbaek White Alvin, Barron Andrew R
Energy Safety Research Institute, Swansea University Bay Campus Swansea SA1 8EN Wales UK
Department of Chemistry, Department of Materials Science and Nanoengineering, Rice University Houston Texas 77007 USA.
Nanoscale Adv. 2021 Jan 2;3(3):643-646. doi: 10.1039/d0na01021a. eCollection 2021 Feb 10.
Multi-walled carbon nanotubes (MWCNTs) show an oscillation in electrical resistance (from - measurements) during mechanical distortion in which peak separation is inversely correlated with the diameter of the MWCNTs. These results provide the first experimental support of the theoretical prediction that distortion causes Van Hove singularities and Dirac cones in MWCNTs to misalign and cause the opening of the band gap, and suggest that when fabricating contacts for CNTs for device applications, the pressure caused by the contact deposition method must be taken into account for manufacturing devices with consistent properties.
多壁碳纳米管(MWCNTs)在机械变形过程中表现出电阻振荡(来自测量),其中峰值间距与MWCNTs的直径成反比。这些结果为理论预测提供了首个实验支持,即变形会导致MWCNTs中的范霍夫奇点和狄拉克锥不对齐并导致带隙打开,并表明在为器件应用制造碳纳米管触点时,必须考虑接触沉积方法引起的压力,以制造具有一致性能的器件。