Liu Yanwen, Li Fen, Tian Hong, Wang Guojian, Wang Xiaoxia
Aerospace Information Research Institute, Chinese Academy of Sciences Beijing 101407 China
Nanoscale Adv. 2022 Jun 27;4(17):3517-3523. doi: 10.1039/d2na00338d. eCollection 2022 Aug 23.
Photocathodes are mainly used in such hi-tech fields as photoelectric conversion devices, radiation detection, and accelerators. Laser-driven photocathodes are characterized by low emission, high brightness, easy control, rapid response, , and are hopeful to become satisfactory electron sources for next-generation high-frequency miniaturized electric vacuum microwave devices, to effectively improve the performance and rapid response capability of the devices. For this reason, based on previous research efforts on photocathodes, we proposed an idea that ion beam surface treatment technology was used to modify the substrate surface of photocathodes and make the surface textured, enhancing the light absorptivity and alkali metal adsorption performance of photocathodes, so as to improve their emission performance. The surface appearance of photocathodes was analyzed using the scanning electron microscope (SEM) method, and it was found that the surface of oxygen-free copper treated by ion bombardment had a nanocone structure. The photoemission characteristics of photocathodes before and after the treatment of the surface of oxygen-free copper were studied. Before and after the treatment, the maximum photoemission current densities under stable emission performance of the photocathode were 60.5 mA cm and 146.0 mA cm, respectively, and the calculated quantum efficiencies were 2.67 × 10 and 1.71 × 10, respectively. The quantum efficiency of the photocathode was increased by 5.41 times after the ion surface treatment. The results show that the photoemission quantum efficiency of the oxygen-free copper surface was increased greatly after modification. It was believed through analysis that the main cause for the increase in quantum efficiency was the enhancement of light absorptivity and the increase in the emission surface area.
光电阴极主要应用于光电转换器件、辐射探测和加速器等高科技领域。激光驱动的光电阴极具有发射率低、亮度高、易于控制、响应速度快等特点,有望成为下一代高频小型化电真空微波器件理想的电子源,有效提高器件的性能和快速响应能力。基于此前对光电阴极的研究工作,我们提出利用离子束表面处理技术对光电阴极的衬底表面进行改性,使其表面形成纹理,增强光电阴极的光吸收能力和碱金属吸附性能,从而提高其发射性能。采用扫描电子显微镜(SEM)方法分析了光电阴极的表面形貌,发现经离子轰击处理的无氧铜表面具有纳米锥结构。研究了无氧铜表面处理前后光电阴极的光发射特性。处理前后,光电阴极在稳定发射性能下的最大光发射电流密度分别为60.5 mA/cm²和146.0 mA/cm²,计算得到的量子效率分别为2.67×10⁻⁴和1.71×10⁻³。离子表面处理后,光电阴极的量子效率提高了5.41倍。结果表明,改性后无氧铜表面的光发射量子效率大幅提高。通过分析认为,量子效率提高的主要原因是光吸收能力增强和发射表面积增加。