Song Shiqi, Ye Lingting, Xie Kui
Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China.
University of Chinese Academy of Sciences, Beijing 100049, China.
Membranes (Basel). 2022 Aug 23;12(9):822. doi: 10.3390/membranes12090822.
Oxidative coupling of methane can produce various valuable products, such as ethane and ethylene, and solid oxide electrolysis cells (SOECs) can electrolyze CH to produce CH and CH. In this work, SrFeMoO electrode materials were prepared by impregnation and in situ precipitation, and SrFeMoO was taken as a reference to study the role of metal-oxide interfaces in the catalytic process. When the Fe/SrFeMoO interface is well constructed, the selectivity for C can reach 78.18% at 850 °C with a potential of 1.2 V, and the conversion rate of CH is 11.61%. These results further prove that a well-constructed metal-oxide interface significantly improves the catalytic activity and facilitates the reaction.
甲烷的氧化偶联可以产生各种有价值的产物,如乙烷和乙烯,而固体氧化物电解池(SOECs)可以电解CH以产生CH和CH。在这项工作中,通过浸渍和原位沉淀制备了SrFeMoO电极材料,并以SrFeMoO作为参考来研究金属-氧化物界面在催化过程中的作用。当Fe/SrFeMoO界面构建良好时,在850℃、1.2V的电位下,C的选择性可达78.18%,CH的转化率为11.61%。这些结果进一步证明,构建良好的金属-氧化物界面显著提高了催化活性并促进了反应。