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量子化:历史与问题。

Quantization: History and problems.

机构信息

Department of Physics, The George Washington University, 725 21st St. NW, 20052, Washington, D.C., United States.

出版信息

Stud Hist Philos Sci. 2022 Dec;96:35-50. doi: 10.1016/j.shpsa.2022.09.001. Epub 2022 Sep 22.

Abstract

In this work, I explore the concept of quantization as a mapping from classical phase space functions to quantum operators. I discuss the early history of this notion of quantization with emphasis on the works of Schrödinger and Dirac, and how quantization fit into their overall understanding of quantum theory in the 1920's. Dirac, in particular, proposed a quantization map which should satisfy certain properties, including the property that quantum commutators should be related to classical Poisson brackets in a particular way. However, in 1946, Groenewold proved that Dirac's mapping was inconsistent, making the problem of defining a rigorous quantization map more elusive than originally expected. This result, known as the Groenewold-Van Hove theorem, is not often discussed in physics texts, but here I will give an account of the theorem and what it means for potential ``corrections" to Dirac's scheme. Other proposals for quantization have arisen over the years, the first major one being that of Weyl in 1927, which was later developed by many, including Groenewold, and which has since become known as Weyl Quantization in the mathematical literature. Another, known as Geometric Quantization, formulates quantization in differential-geometric terms by appealing to the character of classical phase spaces as symplectic manifolds; this approach began with the work of Souriau, Kostant, and Kirillov in the 1960's. I will describe these proposals for quantization and comment on their relation to Dirac's original program. Along the way, the problem of operator ordering and of quantizing in curvilinear coordinates will be described, since these are natural questions that immediately present themselves when thinking about quantization.

摘要

在这项工作中,我探讨了量子化的概念,即将经典相空间函数映射到量子算符的过程。我讨论了这个量子化概念的早期历史,重点介绍了薛定谔和狄拉克的工作,以及量子化如何融入他们在 20 世纪 20 年代对量子理论的整体理解。特别是,狄拉克提出了一种量子化映射,该映射应满足某些性质,包括量子对易子应与经典泊松括号以特定方式相关的性质。然而,在 1946 年,格罗宁根证明了狄拉克的映射是不一致的,这使得定义严格的量子化映射的问题比最初预期的更加棘手。这个结果,即格罗宁根-范霍夫定理,在物理教材中并不常被讨论,但在这里我将介绍这个定理以及它对狄拉克方案的潜在“修正”意味着什么。多年来,已经提出了其他的量子化方案,第一个主要的方案是 1927 年魏尔提出的,后来被许多人发展,包括格罗宁根,并且从那时起,在数学文献中就被称为魏尔量子化。另一个,被称为几何量子化,通过诉诸经典相空间作为辛流形的性质,以微分几何术语来表述量子化;这种方法始于 20 世纪 60 年代苏里亚乌、科斯塔特和基里洛夫的工作。我将描述这些量子化方案,并评论它们与狄拉克原始方案的关系。在这个过程中,算子排序和曲线坐标下的量子化问题将被描述,因为这些问题是在思考量子化时自然会出现的问题。

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