Sornmek Pariya, Phromyothin Darinee, Supadech Jakrapong, Tantisantisom Kittipong, Boonkoom Thitikorn
College of Materials Innovation and Technology, King Mongkut's Institute of Technology Ladkrabang, Bangkok, Thailand.
National Electronics and Computer Technology Center, National Science and Technology Development Agency, Pathum Thani, Thailand.
Phys Chem Chem Phys. 2022 Oct 19;24(40):24866-24872. doi: 10.1039/d2cp02748h.
Ability to control ionic current flowing through a nanopore has been demonstrated using the electric field effect on an electrical gate surrounding the nanopore. The gate electrode was introduced onto a single nanopore by depositing an Au layer on a silicon nitride diaphragm prior to pore milling using a focused ion beam technique. A hafnium oxide layer was subsequently deposited onto the nanopore structure as an insulating layer to protect the gate electrode. The device operation was investigated in KCl electrolyte and the ionic current regulating ability was examined under the influence of the gate voltage and the nanopore size. It was found that the device shows significant ionic current response with respect to the applied gate voltage. The resulting electric field dependent behavior of the fabricated nanopore suggests that the ionic current is influenced by positive surface charge inside the nanopore. The gate influence was more pronounced in the smaller nanopore and with higher source-drain voltage. The gate and pore size dependence behavior allows the potential to regulate ionic current as a nanoscale valve in nanochannel applications.
利用电场对围绕纳米孔的电栅极的作用,已证明能够控制流经纳米孔的离子电流。通过在使用聚焦离子束技术进行孔铣削之前,在氮化硅隔膜上沉积金层,将栅电极引入单个纳米孔中。随后在纳米孔结构上沉积一层氧化铪作为绝缘层,以保护栅电极。在氯化钾电解质中研究了该器件的运行情况,并在栅极电压和纳米孔尺寸的影响下考察了离子电流调节能力。发现该器件对施加的栅极电压表现出显著的离子电流响应。所制备纳米孔的电场依赖性行为表明,离子电流受纳米孔内正表面电荷的影响。在较小的纳米孔和较高的源漏电压下,栅极影响更为明显。栅极和孔径的依赖性行为使得在纳米通道应用中作为纳米级阀门调节离子电流成为可能。