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镓基液态金属在催化领域的最新进展。

Recent progress of Ga-based liquid metals in catalysis.

作者信息

Sun Xi, Li Hui

机构信息

Dalian Institute of Chemical Physic, CAS Dalian 116023 China

出版信息

RSC Adv. 2022 Sep 1;12(38):24946-24957. doi: 10.1039/d2ra04795k. eCollection 2022 Aug 30.

Abstract

Within the last decade, the application of gallium-based liquid metals in catalysis has received great attention from around the world. This article provides an overview concerning Ga-based liquid metals (LMs) in energy and environmental applications, such as the catalytic synthesis of ethylene by non-petroleum routes Pd-Ga liquid catalysts, alkane dehydrogenation Pd-Ga or Pt-Ga catalysts, CO hydrogenation to methanol Ni Ga or Pd/GaO catalysts, and catalytic degradation of CO EGaIn liquid metal catalysts below 500 °C, where Ga-based liquid metal catalysts exhibit high selectivity and low energy consumption. The formation of isolated metal sites in a liquid metal matrix allows the integration of several characteristics of multiphase catalysis (particularly the operational friendliness of product separation procedures) with those of homogeneous catalysis. In the end, this article sheds light on future prospects, opportunities, and challenges of liquid metal catalysis.

摘要

在过去十年中,镓基液态金属在催化领域的应用受到了全球的广泛关注。本文综述了镓基液态金属在能源和环境应用中的情况,例如通过非石油路线催化合成乙烯(钯-镓液态催化剂)、烷烃脱氢(钯-镓或铂-镓催化剂)、一氧化碳加氢制甲醇(镍-镓或钯/氧化镓催化剂)以及在500℃以下催化降解一氧化碳(镓铟液态金属催化剂),其中镓基液态金属催化剂表现出高选择性和低能耗。液态金属基质中孤立金属位点的形成使得多相催化的几个特性(特别是产物分离程序的操作便利性)与均相催化的特性得以整合。最后,本文阐述了液态金属催化的未来前景、机遇和挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9282/9434383/7fe40e7211d9/d2ra04795k-f1.jpg

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