Zhu Runtian, Li Xiaolu, Wu Cankun, Du Longji, Du Xusheng, Tafsirojjaman T
Key Laboratory for Transport Industry of Bridge Detection Reinforcement Technology, Chang'an University, Xi'an 710064, China.
Zhuhai Communication Group, Zhuhai 519000, China.
Polymers (Basel). 2022 Sep 28;14(19):4072. doi: 10.3390/polym14194072.
In this work, the effect of a hydrothermal environment on mechanical properties and the electrical response behavior of continuous carbon fiber/epoxy (CFRE) composite produced by the pultrusion method were investigated. Due to the relatively uniform distribution of fibers and lack of resin-rich interlayer area, this effect for the pultruded CFRE composite plates is different from the common CFRE laminated composites. Firstly, its hygroscopicity behavior was studied. The absorption ratio increases rapidly to 1.02% within 3 days before reaching a relatively stable state. A three-point bending test, a Vickers hardness test, a thermogravimetric analysis (TGA), and a scanning electron microscope (SEM) analysis were performed to investigate the effect of the hydrothermal environment on the mechanical properties and thermal stability of the CFRE composite. The results indicated that the bending strength decreased quickly within 3 days of hydrothermal treatment, followed by a stable trend, which coincided with that of the hygroscopicity behavior of the composites. The fracture surface analysis indicated that the interfacial properties of carbon fibers in the epoxy matrix were decreased after the hydrothermal treatment, and more carbon fibers could be pulled out from the CFRE in the hygroscopic state. After the hydrothermal treatment, the micro-hardness of the composites was reduced by 25%. TGA confirmed the decreased thermal stability of the CFRE composites after the hydrothermal treatment as well. Moreover, the hydrothermally treated CFRE composites could a reach stable resistance response more readily. The revealing of the effect of moisture and hot environment on the mechanical properties and electrical response behavior of pultruded CFRE composites prepares the ground for their design and practical application in the corresponding environment.
在本研究中,研究了水热环境对拉挤法制备的连续碳纤维/环氧树脂(CFRE)复合材料的力学性能和电响应行为的影响。由于纤维分布相对均匀且缺乏富树脂中间层区域,拉挤CFRE复合材料板的这种影响与普通CFRE层压复合材料不同。首先,研究了其吸湿行为。吸湿率在3天内迅速增加至1.02%,然后达到相对稳定状态。进行了三点弯曲试验、维氏硬度试验、热重分析(TGA)和扫描电子显微镜(SEM)分析,以研究水热环境对CFRE复合材料力学性能和热稳定性的影响。结果表明,水热处理3天内弯曲强度迅速下降,随后呈稳定趋势,这与复合材料的吸湿行为一致。断口表面分析表明,水热处理后环氧树脂基体中碳纤维的界面性能下降,吸湿状态下更多的碳纤维可以从CFRE中拔出。水热处理后,复合材料的显微硬度降低了25%。TGA也证实了水热处理后CFRE复合材料的热稳定性下降。此外,水热处理的CFRE复合材料能更容易地达到稳定的电阻响应。揭示水分和热环境对拉挤CFRE复合材料力学性能和电响应行为的影响,为其在相应环境中的设计和实际应用奠定了基础。