Zhu Runtian, Li Xiaolu, Wu Cankun, Du Longji, Du Xusheng
Key Laboratory for Transport Industry of Bridge Detection Reinforcement Technology, Chang'an University, Xi'an 710064, China.
Zhuhai Communication Group, Zhuhai 519000, China.
Polymers (Basel). 2022 Oct 21;14(20):4452. doi: 10.3390/polym14204452.
The Joule heating behavior of the carbon fiber/epoxy composite (CF/EP) was studied in this work, as well as their influence on the in-situ mechanical properties of the composites and their de-icing performance. The equilibrium temperature of the CF/EP composite could be conveniently adjusted by tuning the current according to the Joule's law. Dynamic mechanical analysis (DMA) tests indicated that the rigidity and stiffness of the fiber-reinforced composite decreased with increasing temperature, and the glass transition temperature (Tg) of the composites was around 104 °C. It was found that the flexural properties of the composites in situ, measured under the electric-current loading, depended on the current value in the range of room temperature to Tg. With increasing the loading current, either the flexural modulus or strength of CF/EP decreased gradually. Such results could be explained that the higher current loading, the larger Joule heat, led to the higher operating temperature of the composite samples and the evolution of their mechanical properties accordingly. Vickers hardness tests indicated that the micro-hardness of the composite decreased with the increase of the operating temperature, which coincided with the evolution of its flexural properties with the electric-current loading. The dependence of the failure behaviors of the CF/EP on the loading current was revealed by the analysis of their fractured surface, where micro-buckling, kinking, fiber pull-out and breakage were involved. A preliminary study indicated that less energy was consumed for the deicing of the same amount of the ice with the CF/EP composite in the case of less electric-current loading. The research on the Joule heating effect of CF/EP and their corresponding mechanical properties benefits the design and direct application of the composites under the electric-current loading.
本工作研究了碳纤维/环氧树脂复合材料(CF/EP)的焦耳热行为,以及它们对复合材料原位力学性能及其除冰性能的影响。根据焦耳定律,通过调节电流可以方便地调节CF/EP复合材料的平衡温度。动态力学分析(DMA)测试表明,纤维增强复合材料的刚性和刚度随温度升高而降低,复合材料的玻璃化转变温度(Tg)约为104℃。研究发现,在室温至Tg范围内,在电流加载下原位测量的复合材料的弯曲性能取决于电流值。随着加载电流的增加,CF/EP的弯曲模量和强度均逐渐降低。这样的结果可以解释为,电流加载越高,焦耳热越大,导致复合材料样品的工作温度越高,其力学性能也相应发生变化。维氏硬度测试表明,复合材料的显微硬度随工作温度的升高而降低,这与复合材料在电流加载下弯曲性能的变化一致。通过对CF/EP断裂表面的分析揭示了其失效行为对加载电流的依赖性,其中涉及微屈曲、扭结、纤维拔出和断裂。初步研究表明,在较小电流加载情况下,用CF/EP复合材料去除相同量的冰消耗的能量较少。对CF/EP的焦耳热效应及其相应力学性能的研究有利于复合材料在电流加载下的设计和直接应用。