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具有高拉伸强度和改善水溶性的热塑性淀粉凝胶薄膜的制备。

Production of Thermoplastic Starch- Gel Film with High Tensile Strength and Improved Water Solubility.

作者信息

Abd Karim Siti Fatma, Idris Juferi, Jai Junaidah, Musa Mohibah, Ku Hamid Ku Halim

机构信息

School of Chemical Engineering, College of Engineering, Universiti Teknologi MARA (UiTM), Shah Alam 40450, Selangor, Malaysia.

School of Chemical Engineering, College of Engineering, Universiti Teknologi MARA (UiTM), Sarawak Branch, Samarahan Campus, Kota Samarahan 94300, Sarawak, Malaysia.

出版信息

Polymers (Basel). 2022 Oct 8;14(19):4213. doi: 10.3390/polym14194213.

Abstract

Biodegradable film packaging made from thermoplastic starch (TPS) has low mechanical performance and high water solubility, which is incomparable with synthetic films. In this work, (AV) gel and plasticized soluble potato starch were utilised to improve the mechanical stability and water solubility of TPS. Dried starch was mixed with glycerol and different AV gel concentrations (0% to 50%). The TPS + 50% AV gel (30 g TPS + 15 g AV gel) showed the best improvement compared to TPS alone. When compared to similar TPS films with AV gel added, this film is stronger and dissolves better in water. Mechanical qualities improved the tensile strength and Young's modulus of the TPS film, with 1.03 MPa to 9.14 MPa and 51.92 MPa to 769.00 MPa, respectively. This was supported by the improvement of TPS water solubility from 57.44% to 46.6% and also by the increase in decomposition temperature of the TPS. This promises better heat resistance. The crystallinity percentage increase to 24.26% suggested that the formation of hydrogen bonding between TPS and AV gel enhanced crosslinking in the polymeric structure. By adding AV gel, the TPS polymeric structure is improved and can be used as a biodegradable food-packaging film.

摘要

由热塑性淀粉(TPS)制成的可生物降解薄膜包装具有较低的机械性能和较高的水溶性,这与合成薄膜相比是无可比拟的。在这项工作中,利用阿拉伯胶(AV)凝胶和增塑的可溶性马铃薯淀粉来提高TPS的机械稳定性和水溶性。将干燥的淀粉与甘油和不同浓度(0%至50%)的AV凝胶混合。与单独的TPS相比,TPS + 50% AV凝胶(30克TPS + 15克AV凝胶)表现出最佳的改进效果。与添加了AV凝胶的类似TPS薄膜相比,该薄膜更强且在水中的溶解性更好。机械性能提高了TPS薄膜的拉伸强度和杨氏模量,分别从1.03兆帕提高到9.14兆帕,从51.92兆帕提高到769.00兆帕。TPS的水溶性从57.44%提高到46.6%以及TPS分解温度的升高也支持了这一点,这预示着更好的耐热性。结晶度百分比增加到24.26%,表明TPS与AV凝胶之间形成氢键增强了聚合物结构中的交联。通过添加AV凝胶,TPS聚合物结构得到改善,可作为可生物降解的食品包装薄膜使用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beef/9571595/f548fa3a21fd/polymers-14-04213-g001.jpg

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