Adelaide Exposure Science and Health, School of Public Health, University of Adelaide, Adelaide, SA 5031, Australia.
Mawson Analytical Spectrometry Services, School of Physical Sciences, University of Adelaide, Adelaide, SA 5000, Australia.
Ann Work Expo Health. 2023 Feb 13;67(2):288-293. doi: 10.1093/annweh/wxac068.
Engineered stones are often characterized for their crystalline silica content. Their organic composition, particularly that of the emissions generated during fabrication work using hand-held power tools, is relatively unexplored. We forensically screened the emissions from dry-cutting 12 engineered stone products in a test chamber for their organic composition by pyrolysis-gas chromatography-mass spectrometry (GC-MS) plus selected traditional capture and analysis techniques. Phthalic anhydride, which has a Respiratory Sensitization (RSEN) Notation by the American Conference of Governmental Industrial Hygienists (ACGIH), was the most common and abundant compound, at 26-85% of the total organic composition of engineered stone emissions. Benzaldehyde and styrene were also present in all twelve samples. During active cutting, the predominant volatile organic compound (VOC) emitted was styrene, with phthalic anhydride, benzene, ethylbenzene, and toluene also detected. These results have important health implications as styrene and phthalic anhydride are irritants to the respiratory tract. This study suggests a risk of concurrent exposure to high levels of respirable crystalline silica and organic lung irritants during engineered stone fabrication work.
人造石材通常以其二氧化硅含量为特征。其有机成分,特别是使用手持动力工具进行制造工作时产生的排放物的有机成分,尚未得到充分研究。我们通过热裂解-气相色谱-质谱联用(GC-MS)和一些传统的捕获和分析技术,对 12 个人造石材产品在测试室中进行干切时产生的排放物的有机成分进行了法医筛查。邻苯二甲酸酐是美国政府工业卫生学家会议(ACGIH)具有呼吸道致敏(RSEN)标记的物质,是最常见和最丰富的化合物,占人造石材排放物总有机成分的 26-85%。所有 12 个样本中都存在苯甲醛和苯乙烯。在主动切割过程中,主要排放的挥发性有机化合物(VOC)是苯乙烯,同时还检测到邻苯二甲酸酐、苯、乙苯和甲苯。这些结果具有重要的健康意义,因为苯乙烯和邻苯二甲酸酐会刺激呼吸道。本研究表明,在人造石材制造过程中,同时接触高浓度可吸入结晶二氧化硅和有机肺部刺激物的风险。