Solute-induced strengthening during creep of an aged-hardened Al-Mn-Zr alloy.

We examine the precipitation and creep behavior of (at.%) alloys, with and without the L1-forming elements Zr and Er (0.09 and 0.05 at.%, respectively), utilizing isochronal aging experiments as well as compressive and tensile creep tests performed between 275 and 400 °C. The alloy exhibits an unusually high creep resistance in the peak-aged state, which is significantly better than that observed generally in its Mn-free L1-strengthened counterparts; for example, the creep threshold stresses at 300 °C are 34-37 MPa, about three times higher than those in a Mn-free alloy. Scanning transmission electron microscopy illustrates that nanoscale -precipitates are formed in the dendritic cores and micron-sized precipitates in the inter-dendritic channels. Moreover, the Al(f.c.c.)-matrix remains supersaturated with randomly distributed Mn solute atoms, as determined by atom-probe tomography and electrical conductivity measurements, for months at creep temperatures. Creep experiments on the Zr- and Er-free solid-solution alloy reveal a small primary creep strain, a high apparent stress exponent, n ~9-7, and a threshold-stress-type behavior. After ruling out other possible mechanisms, we provide evidence that the threshold stress in this precipitate-free alloy originates from dislocation/solute elastic interactions leading to a strong drag force exerted on edge dislocations, hindering their ability to climb. The relatively high creep resistance of is interpreted in terms of the synergy between this solute-induced threshold stress (, from Mn in solid-solution) and the known precipitate-bypass threshold stress (from the L1-nanoprecipitates).