Evolution of the Hierarchical Molecular Structures of Tectonically Deformed Coals: Insights from First-Order Raman Spectra.

The dynamic metamorphism of tectonically deformed coals (TDCs) is closely correlated with the occurrence of coalbed methane. Here, a Raman detection technique was used to characterize two primary coals and 14 TDCs sampled from the Huaibei coalfield, allowing for profound insight into the dynamic metamorphism caused by tectonic stress in coals. A nine-peak curve fitting method was applied to deconvolute the first-order Raman spectra, and six structural parameters were used to characterize the hierarchical evolution of TDC molecules. The lower / and / ratios in TDCs indicate that the cross-links in secondary and aggregated (outer) structures are cleaved by tectonic stress. Once the aromatic structures are released through the cleavage of cross-links, the outer structures can be rearranged into a more ordered configuration, as indicated by the higher / ratio in TDCs. Additionally, the basic structural units (including aromatic structures and side chains) in TDC are also altered by stress. The increasing values of / and / illustrate that the size of aromatic structures and the ratio of small aromatic structures both increase with increasing coal deformation intensity. The value of / decreases with increasing deformation intensity, indicating that oxygen functional groups are disassociated by tectonic stress. However, as the basic structural units are commonly rigid and cannot be altered as readily as the outer structures, the evolution of basic structural units is not always obvious in weakly deformed coals (such as cataclastic, mortar, and schistose types) but is more significant in strongly deformed coals (such as granulitic, scaly, and wrinkle types).