Advantages of Structure and Electrochemical Properties of Graphene Prepared from Tectonically Deformed Coal.

Asa low-cost carbon-rich resource, coal has been widely used to prepare excellent electrochemical energy-storage carbon materials such as graphene. However, the different structures of carbon source will affect the performance of carbon materials. To explore the feasibility of preparing high-performance graphene from the carbon source affected by tectonic stress in coal, in this paper, series products of coal-based graphene are prepared by tectonically deformed coal (TDC) and normal structural coal (NSC). The structural parameters are characterized by HRTEM, XRD, Raman, and low-temperature CO and N adsorption, and the electrochemical performance of coal-based graphene lithium battery is tested by galvanostatic charge-discharge and cyclic voltammetry. The results show that tectonic stress makes the proportion of the medium-long aromatic fringes, preferred orientation degree (POD), and multilayer stacking in TDC aromatic fringes slightly higher than those in NSC. At the same temperature, the relatively large microcrystalline size, the high order degree, and more pore structures make the local molecular oriented (LMO) domain vertical height () and graphitization degree () of the coal-based graphite microcrystalline structure prepared by TDC better than those of NSC, which indicates that the carbon source in TDC contains more graphitizable carbon structures. This makes the graphene prepared by TDC not only possess perfectly ordered crystal planes but also relatively abundant nanochannels. High lithium-storage capacity and low charge-transfer resistance make the electrochemical performance of graphene prepared by TDC as an anode electrode material for lithium-ion batteries superior to that by NSC.