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用于碱性介质中析氧反应的钙钛矿基电催化剂:一篇综述。

Perovskite-based electrocatalysts for oxygen evolution reaction in alkaline media: A mini review.

作者信息

Kim Dongkyu, Oh Lee Seul, Park Jong Hyeok, Kim Hyung Ju, Lee Seonggyu, Lim Eunho

机构信息

Chemical & Process Technology Division, Korea Research Institute of Chemical Technology (KRICT), Daejeon, South Korea.

Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul, South Korea.

出版信息

Front Chem. 2022 Oct 7;10:1024865. doi: 10.3389/fchem.2022.1024865. eCollection 2022.

Abstract

Water electrolysis is one of the attractive technologies for producing clean and sustainable hydrogen fuels with high purity. Among the various kinds of water electrolysis systems, anion exchange membrane water electrolysis has received much attention by combining the advantages of alkaline water electrolysis and proton exchange membrane water electrolysis. However, the sluggish kinetics of the oxygen evolution reaction, which is based on multiple and complex reaction mechanisms, is regarded as a major obstacle for the development of high-efficiency water electrolysis. Therefore, the development of high-performance oxygen evolution reaction electrocatalysts is a prerequisite for the commercialization and wide application of water electrolysis systems. This mini review highlights the current progress of representative oxygen evolution reaction electrocatalysts that are based on a perovskite structure in alkaline media. We first summarize the research status of various kinds of perovskite-based oxygen evolution reaction electrocatalysts, reaction mechanisms and activity descriptors. Finally, the challenges facing the development of perovskite-based oxygen evolution reaction electrocatalysts and a perspective on their future are discussed.

摘要

水电解是生产高纯度清洁且可持续氢燃料的有吸引力的技术之一。在各种水电解系统中,阴离子交换膜水电解通过结合碱性水电解和质子交换膜水电解的优点而备受关注。然而,基于多重复杂反应机制的析氧反应动力学缓慢,被认为是高效水电解发展的主要障碍。因此,开发高性能析氧反应电催化剂是水电解系统商业化和广泛应用的先决条件。本综述重点介绍了碱性介质中基于钙钛矿结构的代表性析氧反应电催化剂的当前进展。我们首先总结了各种基于钙钛矿的析氧反应电催化剂的研究现状、反应机制和活性描述符。最后,讨论了基于钙钛矿的析氧反应电催化剂开发面临的挑战及其未来展望。

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