腈的形成：二氯卡宾插入到镧系元素（III）双（三甲基硅基）酰胺配合物的硅-氮键中。
Nitrile formation dichlorocarbene insertion into the Si-N bond of Ln(III) bis(trimethylsilyl)amide complexes.
作者信息
Li Yangjuan, Gong Yu
机构信息
Department of Radiochemistry, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800, China.
出版信息
Chem Commun (Camb). 2022 Nov 10;58(90):12552-12555. doi: 10.1039/d2cc04538a.
PMID:36285696
Abstract
The reactions of Ln[N(SiMe)] (Ln = Eu, Sm, Yb) with chloroform yield the [Ln{N(SiMe)}(μ-Cl)(NCSiMe)] (Ln = Eu(1), Sm(2)) and YbN(SiMe) (3) complexes, all of which contain two neutral MeSiCN ligands. The unexpected formation of the MeSiCN ligand represents a rare example of nitrile formation through the insertion of dichlorocarbene into the Si-N bond.
摘要
Ln[N(SiMe)]（Ln = Eu、Sm、Yb）与氯仿反应生成[Ln{N(SiMe)}(μ-Cl)(NCSiMe)]（Ln = Eu(1)、Sm(2)）和YbN(SiMe)（3）配合物，所有这些配合物都含有两个中性的MeSiCN配体。MeSiCN配体的意外形成是二氯卡宾插入Si-N键形成腈的罕见例子。
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