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具有大二阶非线性光学性质的发光1,10-菲咯啉β-二酮铕配合物

Luminescent 1,10-Phenanthroline β-Diketonate Europium Complexes with Large Second-Order Nonlinear Optical Properties.

作者信息

Fagnani Francesco, Colombo Alessia, Malandrino Graziella, Dragonetti Claudia, Pellegrino Anna Lucia

机构信息

Dipartimento di Chimica, Università di Milano and INSTM UdR Milano, 20126 Milan, Italy.

Dipartimento di Scienze Chimiche, Università di Catania and INSTM UdR Catania, 95125 Catania, Italy.

出版信息

Molecules. 2022 Oct 18;27(20):6990. doi: 10.3390/molecules27206990.

DOI:10.3390/molecules27206990
PMID:36296583
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9610016/
Abstract

Substitution of the diglyme ligand of [Eu(hfa)(diglyme)] (where hfa is hexafluoroacetylacetonate) with a simple 1,10-phenanthroline leads to a six-fold increase of the product μβ, as measured by the Electric-Field-Induced Second Harmonic generation (EFISH) technique. Similarly, [Eu(tta)(1,10-phenanthroline)] (where Htta is 2-thenoyltrifluoroacetone) is characterized by a large second-order NLO response. Both 1,10-phenanthroline europium complexes have great potential as multifunctional materials for photonics.

摘要

用简单的1,10 - 菲咯啉取代[Eu(hfa)(二甘醇二甲醚)]（其中hfa为六氟乙酰丙酮）中的二甘醇二甲醚配体，通过电场诱导二次谐波产生（EFISH）技术测量，产物μβ增加了六倍。同样，[Eu(tta)(1,10 - 菲咯啉)]（其中Htta为2 - 噻吩甲酰三氟丙酮）具有较大的二阶非线性光学响应。两种1,10 - 菲咯啉铕配合物作为光子学多功能材料都具有巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa1/9610016/982131dd4a11/molecules-27-06990-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa1/9610016/684ac6301472/molecules-27-06990-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa1/9610016/3e201062ed7c/molecules-27-06990-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa1/9610016/27b5c5ddd2ad/molecules-27-06990-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa1/9610016/982131dd4a11/molecules-27-06990-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa1/9610016/684ac6301472/molecules-27-06990-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa1/9610016/3e201062ed7c/molecules-27-06990-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa1/9610016/27b5c5ddd2ad/molecules-27-06990-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa1/9610016/982131dd4a11/molecules-27-06990-g004.jpg

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Materials (Basel). 2023 Oct 27;16(21):6889. doi: 10.3390/ma16216889.
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4
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7
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10
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Chem Commun (Camb). 2013 Feb 25;49(16):1600-2. doi: 10.1039/c2cc35247h.