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超分子聚合物能否成为聚合物驱提高采收率的另一种材料选择?

Can Supramolecular Polymers Become Another Material Choice for Polymer Flooding to Enhance Oil Recovery?

作者信息

Sun Linghui, Zhang Zhirong, Leng Kaiqi, Li Bowen, Feng Chun, Huo Xu

机构信息

Development Research Institute, Research Center for Enhanced Oil Recovery of China Petroleum Exploration, Beijing 100089, China.

Institute of Seepage Fluid Mechanics, Chinese Academy of Sciences, Langfang 065000, China.

出版信息

Polymers (Basel). 2022 Oct 18;14(20):4405. doi: 10.3390/polym14204405.

Abstract

High molecular polymers have been widely studied and applied in the field of enhanced oil recovery (EOR). At present, the focus of research has been changed to the design of polymer networks with unique properties such as anti-temperature and anti-salinity, good injection and so on. Supramolecular polymers have high viscoelasticity as well as excellent temperature, salt resistance and injection properties. Can supramolecular polymers become another material choice for polymer flooding to enhance oil recovery? The present review aims to systematically introduce supramolecular polymers, including its design strategy, interactions and rheological properties, and address three main concerns: (1) Why choose supramolecular polymers? (2) How do we synthesize and characterize supramolecular polymers in the field of oilfield chemistry? (3) What has been the application progress of supramolecular polymers in improving oil recovery? The introduction of a supramolecular interaction system provides a new idea for polymer flooding and opens up a new research direction to improve oil recovery. Aiming at the "reversible dynamic" supramolecular polymers, the supramolecular polymers are compared with the conventional covalent macromolecular polymer networks, and the challenges and future research directions of supramolecular polymers in EOR are discussed. Finally, the author's viewpoints and perspectives in this emerging field are discussed.

摘要

高分子聚合物在提高采收率(EOR)领域已得到广泛研究和应用。目前,研究重点已转向具有抗温、抗盐、良好注入性等独特性能的聚合物网络设计。超分子聚合物具有高粘弹性以及优异的温度、盐抗性和注入性能。超分子聚合物能否成为聚合物驱提高采收率的另一种材料选择?本综述旨在系统介绍超分子聚合物,包括其设计策略、相互作用和流变性能,并解决三个主要问题:(1)为何选择超分子聚合物?(2)在油田化学领域如何合成和表征超分子聚合物?(3)超分子聚合物在提高采收率方面的应用进展如何?超分子相互作用体系的引入为聚合物驱提供了新思路,为提高采收率开辟了新的研究方向。针对“可逆动态”超分子聚合物,将超分子聚合物与传统共价大分子聚合物网络进行了比较,并讨论了超分子聚合物在提高采收率方面的挑战和未来研究方向。最后,讨论了作者在这一新兴领域的观点和展望。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/71e1/9611012/8b21899b563d/polymers-14-04405-g001.jpg

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