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简化锂离子可充电电池的电极设计。

Simplifying Electrode Design for Lithium-Ion Rechargeable Cells.

作者信息

Zheng Tianye, Boles Steven T

机构信息

Department of Electrical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon 999077, Hong Kong.

Department of Energy and Process Engineering, Norwegian University of Science and Technology, Høgskoleringen 1, 7491 Trondheim, Norway.

出版信息

ACS Omega. 2022 Oct 11;7(42):37867-37872. doi: 10.1021/acsomega.2c04966. eCollection 2022 Oct 25.

Abstract

In the race to increase lithium-ion cell manufacturing, labor and energy costs quickly ascend to become chief concerns for building new facilities, as conventional electrode designs need significant resources during fabrication. Complicating this issue is an empirical trade-off between environmental friendliness and ethical sourcing. To circumvent this paradox, modified cell designs that employ foils and textiles can significantly change manufacturing considerations if their simple construction can be matched with competitive performance. In this work, we demonstrate one possible cell design for a lithium-ion device that utilizes a fabric and a foil for the cathode and the anode, respectively. For the anode, a prelithiated aluminum foil is chosen, as the room-temperature solubility range of the LiAl phase is well-suited to uptake and release lithium, all while reducing energy or cost-intensive production steps. The cathode is composed of activated carbon fiber textiles, which offer a scalable path to realize sustainability. With such benefits, this device design can potentially change the calculus for the mass production of energy storage devices.

摘要

在提高锂离子电池制造能力的竞争中,劳动力和能源成本迅速上升,成为建设新工厂的主要担忧,因为传统电极设计在制造过程中需要大量资源。使这个问题更加复杂的是,在环境友好性和道德采购之间存在着一种经验性的权衡。为了规避这一矛盾,如果采用箔片和纺织品的改良电池设计能够以简单的结构实现具有竞争力的性能,那么它们就能显著改变制造方面的考量。在这项工作中,我们展示了一种用于锂离子装置的可能的电池设计,该设计分别使用织物和箔片作为阴极和阳极。对于阳极,选择预锂化铝箔,因为LiAl相的室温溶解度范围非常适合锂的吸收和释放,同时还能减少能源或成本密集型的生产步骤。阴极由活性炭纤维织物组成,这为实现可持续性提供了一条可扩展的途径。有了这些优点,这种装置设计有可能改变储能装置大规模生产的计算方式。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b14/9607682/e50f259268d2/ao2c04966_0002.jpg

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