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用于增强直接硼氢化物燃料电池性能的具有纹理结构的阴离子交换膜的制备。

Fabrication of an anion exchange membrane with textured structure for enhanced performance of direct borohydride fuel cells.

作者信息

Wei Jinyang, Han Xubin, Li Xingxing, Qin Haiying, Yin Haoyong, Zhang Wen, Ni Hualiang, Wang Xue

机构信息

College of Materials and Environmental Engineering, Hangzhou Dianzi University Hangzhou 310018 P. R. China

Daqing Oilfield Construction Group Co., Ltd Daqing 163453 P. R. China.

出版信息

RSC Adv. 2022 Oct 10;12(44):28707-28711. doi: 10.1039/d2ra04151k. eCollection 2022 Oct 4.

Abstract

Developing electrolyte membranes with a simple preparation process and high performance is a top priority for the commercialization of fuel cells. Inspired by solar cell texturing to improve its conversion efficiency, this study prepares a textured membrane by increasing the roughness of a glass plate. The structures of the textured membrane and the flat membrane are characterized and compared. The membranes are assembled in fuel cells for performance testing. The surface area of the textured membrane is 1.27 times that of the flat membrane, which increases the size of the three-phase boundary in fuel cells. The maximum power density of the fuel cell using the textured membrane is 1.17 times of the cell using the flat membrane at 60 °C. The excellent performance of the cell using the textured membrane profit from the enlargement of the three-phase boundary. This work offers a simple way to develop outstanding-performance membranes by changing their surface roughness.

摘要

开发具有简单制备工艺和高性能的电解质膜是燃料电池商业化的首要任务。受太阳能电池纹理化以提高其转换效率的启发,本研究通过增加玻璃板的粗糙度制备了一种纹理化膜。对纹理化膜和平板膜的结构进行了表征和比较。将这些膜组装在燃料电池中进行性能测试。纹理化膜的表面积是平板膜的1.27倍,这增加了燃料电池中三相边界的尺寸。在60°C时,使用纹理化膜的燃料电池的最大功率密度是使用平板膜的电池的1.17倍。使用纹理化膜的电池的优异性能得益于三相边界的扩大。这项工作提供了一种通过改变膜的表面粗糙度来开发高性能膜的简单方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3cab/9549479/e160f6334da2/d2ra04151k-f1.jpg

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