Hardoüin Jerôme, Doré Claire, Laurent Justine, Lopez-Leon Teresa, Ignés-Mullol Jordi, Sagués Francesc
Departament de Química Física, Universitat de Barcelona, 08028, Barcelona, Spain.
Institute of Nanoscience and Nanotechnology, Universitat de Barcelona, 08028, Barcelona, Spain.
Nat Commun. 2022 Nov 5;13(1):6675. doi: 10.1038/s41467-022-34336-z.
The role of boundary layers in conventional liquid crystals is commonly related to the mesogen anchoring on confining walls. In the classical view, anchoring enslaves the orientational field of the passive material under equilibrium conditions. In this work, we show that an active nematic can develop active boundary layers that topologically polarize the confining walls. We find that negatively-charged defects accumulate in the boundary layer, regardless of the wall curvature, and they influence the overall dynamics of the system to the point of fully controlling the behavior of the active nematic in situations of strong confinement. Further, we show that wall defects exhibit behaviors that are essentially different from those of their bulk counterparts, such as high motility or the ability to recombine with another defect of like-sign topological charge. These exotic behaviors result from a change of symmetry induced by the wall in the director field around the defect. Finally, we suggest that the collective dynamics of wall defects might be described in terms of a model equation for one-dimensional spatio-temporal chaos.
传统液晶中边界层的作用通常与介晶在限制壁上的锚定有关。在经典观点中,在平衡条件下,锚定限制了被动材料的取向场。在这项工作中,我们表明活性向列相可以形成活性边界层,使限制壁发生拓扑极化。我们发现,无论壁的曲率如何,带负电荷的缺陷都会在边界层中积累,并且它们会影响系统的整体动力学,以至于在强限制情况下完全控制活性向列相的行为。此外,我们表明壁缺陷表现出与其本体对应物本质上不同的行为,例如高迁移率或与具有相同符号拓扑电荷的另一个缺陷重新结合的能力。这些奇异行为源于壁在缺陷周围指向矢场中引起的对称性变化。最后,我们建议壁缺陷的集体动力学可以用一维时空混沌的模型方程来描述。